Carbonyl sulfide (OCS) is a non-hygroscopic trace species in the free troposphere and the primary sulfur reservoir maintained by direct oceanic, geologic, biogenic and anthropogenic emissions and the oxidation of other sulfur-containing source species. It’s the largest source of sulfur transported to the stratosphere during volcanically quiescent periods. Data from 22 ground-based globally dispersed stations are used to derive trends in total and partial column OCS. Middle infrared spectral data are recorded by solar-viewing Fourier transform interferometers that are operated as part of the Network for the Detection of Atmospheric Composition Change between 1986 and 2020. Vertical information in the retrieved profiles provides analysis of discreet altitudinal regions. Trends are found to have well-defined inflection points. In two linear trend time periods ~2002 - 2008 and ~2008 - 2016, tropospheric trends range from ~0.0 to (1.55 ± 0.30 %/y) in contrast to the prior period where all tropospheric trends are negative. Regression analyses show strongest correlation in the free troposphere with anthropogenic emissions. Stratospheric trends in the period ~2008 - 2016 are positive up to (1.93 ± 0.26 %/y) except notably low latitude stations that have negative stratospheric trends. Since ~2016, all stations show a free tropospheric decrease to 2020. Stratospheric OCS is regressed with simultaneously measured N$_2$O to derive a trend accounting for dynamical variability. Stratospheric lifetimes are derived and range from (54.1 ± 9.7)y in the sub-tropics to (103.4 ± 18.3)y in Antarctica. These unique long-term measurements provide new and critical constraints on the global OCS budget.

In Gale crater on Mars, the rover Curiosity has discovered evidence of fluid mobilization of the redox-sensitive element manganese. We present results for Mn from Curiosity’s Alpha Particle X-ray Spectrometer (APXS), which show that the average MnO concentration in mudstone-dominated sedimentary units (0.22 wt%) is about one-half of the concentration in the average Mars crust (0.44 wt%). Geochemical trends indicate that Mn in the sedimentary bedrock, most of which has a basaltic provenance, was leached by chemical alteration and dissolution. In >350 vertical meters of mudstone-dominated strata, the apparent leaching of Mn and retention of Fe in Fe-O-H phase(s) resulted in the fractionation of Fe and Mn, indicating relatively moderate Eh-pH fluid conditions that were not highly alkaline, reducing, or oxidizing. Exceptions are fracture-associated, silica-rich haloes where both Mn and Fe were leached by low pH fluids. The rover also discovered Mn-rich veins, nodules, and patchy, dark coatings on rock surfaces, which are variably associated with enrichments in Fe, P, Cl, and/or Zn. These Mn-rich features represent ~1% of the 1,029 APXS measurements acquired over ~25 km of rover traverse. A thermochemical model shows that dissolved Mn2+ could have been concentrated via evaporation, sublimation, and/or freezing. Manganese was then likely precipitated in localized features when > 99.99% of the Mn2+-bearing water was removed from the system. These findings indicate that Mn was mobile in Gale crater and therefore bioavailable as a potential energy source for life.