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Global Atmospheric OCS Trend Analysis from 22 NDACC Stations
  • +31
  • James W Hannigan,
  • Ivan Ortega,
  • Shima Bahramvash Shams,
  • Thomas Blumenstock,
  • John Elliott Campbell,
  • Stephanie Araz Conway,
  • Victoria Flood,
  • Omaira García,
  • Michel Grutter,
  • Frank Hase,
  • Nicholas Brian Jones,
  • Pascal Jeseck,
  • Emmanuel Mahieu,
  • Maria Makarova,
  • Martine De Maziere,
  • Isamu Morino,
  • Isao Murata,
  • Tomoo Nagahama,
  • Hideaki Nakajima,
  • Justus Notholt,
  • Mathias Palm,
  • Anatoliy Poberovskii,
  • Markus Rettinger,
  • John Robinson,
  • Matthias Schneider,
  • Amelie Röhling,
  • Christian Servais,
  • Dan Smale,
  • Wolfgang Stremme,
  • Kimberly Strong,
  • Ralf Sussmann,
  • Yao Té,
  • Corinne Vigouroux,
  • Tyler Wizenberg
James W Hannigan
National Center for Atmospheric Research (UCAR)

Corresponding Author:[email protected]

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Ivan Ortega
National Center for Atmospheric Research (UCAR)
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Shima Bahramvash Shams
NCAR
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Thomas Blumenstock
Karlsruhe Institute for Technology
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John Elliott Campbell
University of California, Merced
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Stephanie Araz Conway
University of Toronto
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Victoria Flood
Univ. Toronto
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Omaira García
Agencia Estatal de Meteorología (AEMET), CIAI
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Michel Grutter
Universidad Nacional Autónoma de México
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Frank Hase
Institut fuer Meteorologie und
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Nicholas Brian Jones
University of Wollongong
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Pascal Jeseck
Sorbonne Université
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Emmanuel Mahieu
University of Liège
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Maria Makarova
Univ. of St. Petersburg
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Martine De Maziere
Belgian Institute for Space Aeronomy
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Isamu Morino
National Institute for Environmental Studies
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Isao Murata
Tohoku University
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Tomoo Nagahama
Institute for Space-Earth Environmental Research, Nagoya University
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Hideaki Nakajima
National Institute for Environmental Studies
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Justus Notholt
Institute of Environmental Physics, University of Bremen
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Mathias Palm
University of Bremen
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Anatoliy Poberovskii
Univ of St. Petersburg
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Markus Rettinger
Karlsruhe Institute of Technology
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John Robinson
NIWA
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Matthias Schneider
Karlsruhe Institute of Technology
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Amelie Röhling
Karlsruhe Institute of Technology
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Christian Servais
University of Liège
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Dan Smale
NIWA Lauder
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Wolfgang Stremme
UNAM, Mexico
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Kimberly Strong
University of Toronto
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Ralf Sussmann
Karlsruhe Institute of Technology, IMK-IFU
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Yao Té
Laboratoire d'Etudes du Rayonnement et de la Matière en Astrophysique et Atmosphères (LERMA-IPSL)
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Corinne Vigouroux
Belgian Institute for Space Aeronomy
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Tyler Wizenberg
University of Toronto
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Abstract

Carbonyl sulfide (OCS) is a non-hygroscopic trace species in the free troposphere and the primary sulfur reservoir maintained by direct oceanic, geologic, biogenic and anthropogenic emissions and the oxidation of other sulfur-containing source species. It’s the largest source of sulfur transported to the stratosphere during volcanically quiescent periods. Data from 22 ground-based globally dispersed stations are used to derive trends in total and partial column OCS. Middle infrared spectral data are recorded by solar-viewing Fourier transform interferometers that are operated as part of the Network for the Detection of Atmospheric Composition Change between 1986 and 2020. Vertical information in the retrieved profiles provides analysis of discreet altitudinal regions. Trends are found to have well-defined inflection points. In two linear trend time periods ~2002 - 2008 and ~2008 - 2016, tropospheric trends range from ~0.0 to (1.55 ± 0.30 %/y) in contrast to the prior period where all tropospheric trends are negative. Regression analyses show strongest correlation in the free troposphere with anthropogenic emissions. Stratospheric trends in the period ~2008 - 2016 are positive up to (1.93 ± 0.26 %/y) except notably low latitude stations that have negative stratospheric trends. Since ~2016, all stations show a free tropospheric decrease to 2020. Stratospheric OCS is regressed with simultaneously measured N$_2$O to derive a trend accounting for dynamical variability. Stratospheric lifetimes are derived and range from (54.1 ± 9.7)y in the sub-tropics to (103.4 ± 18.3)y in Antarctica. These unique long-term measurements provide new and critical constraints on the global OCS budget.
27 Feb 2022Published in Journal of Geophysical Research: Atmospheres volume 127 issue 4. 10.1029/2021JD035764