Surface charging is one of the most common causes of spacecraft anomalies. When and to what potential the spacecraft is charged are two important questions in space weather. Here, for a Chinese geosynchronous navigation satellite, we infer the extreme negative surface charging potentials from the ion differential fluxes measured by a low-energy ion spectrometer. Without the solar eclipse effect away from the midnight, the charging potentials are found to have a negative limit which is determined by the maximum SuperMAG electrojet index in the preceding 2 hr. Such an empirical relation can be reasonably explained by the dependence of 1--50 keV electron fluxes on substorm strength. Similar relations may also exist for other inner magnetospheric spacecraft in the non-eclipse region, which would be useful for spacecraft engineering and space weather alerts.