In well-buffered modern soils, higher annual rainfall is associated with enhanced soil ferrimagnetic mineral content, especially of ultrafine particles that result in distinctive observable rock magnetic properties. Hence, paleosol magnetism has been widely used as a paleoprecipitation proxy. Identifying the dominant mechanism(s) of magnetic enhancement in a given sample is critical for reliable inference of paleoprecipitation. Here we use high-resolution magnetic field and electron microscopy to identify the grain-scale setting and formation pathway of magnetic enhancement in two modern soils developed in higher (~580 mm/y) and lower (~190 mm/y) precipitation settings from the Qilianshan Range, China. We find both soils contain 1-30 µm aeolian Fe-oxide grains with indistinguishable rock magnetic properties while the higher-precipitation soil contains an additional population of ultrafine (<150 nm), magnetically distinct magnetite grains. We show that the in situ precipitation of these ultrafine particles, likely during wet-dry cycling, is the only significant magnetic enhancement mechanism in this soil. These results demonstrate the potential for quantum diamond microscope (QDM) magnetic microscopy to extract magnetic information from distinct, even intimately mixed, grain populations. This information can be used to evaluate the contribution of distinct enhancement mechanisms to the total magnetization.

We report the characterisation of anthropogenic magnetic particulate matter (MPM) collected on leaves from roadside Callistemon trees from Lahore, Pakistan, and on known sources of traffic-related particulates to assess the potential of first-order reversal curve (FORC) diagrams to discriminate between different sources of anthropogenic magnetic particles. Magnetic measurements on leaves indicate the presence of surface-oxidised magnetite spanning the superparamagnetic (< 30 nm) to single-domain (~30-70 nm) to vortex size range (~70-700 nm). Fe-bearing particles are present both as discrete particles on the surface of larger mineral dust or carbonaceous particles and embedded within them, such that their aerodynamic sizes may be decoupled from their magnetic grain sizes. FORC diagrams of brake-pad residue specimens show a distinct combination of narrow central ridge, extending from 0-200 mT, and a low-coercivity, vertically spread signal, attributed to vortex and multi-vortex behaviour of metallic Fe. This is in agreement with scanning electron microscopy results that show the presence of metallic as well as oxidised Fe. Exhaust-pipe residue samples display a more conventional ‘magnetite-like’ signal comprising a lower coercivity central ridge (0-80 mT) and a tri-lobate signal attributed to vortex state and/or magnetostatic interactions. The FORC signatures of leaf samples combine aspects of both exhaust residue and brake-pad endmembers, suggesting that FORC fingerprints have the potential to identify and quantify the relative contributions from exhaust and non-exhaust (brake-wear) emissions. Such measurements may provide a cost-effective way to monitor the changing balance of future particulate emissions as the vehicle fleet is electrified over the coming years.