Inequalities persist in the geosciences. White women and people of color remain under-represented at all levels of academic faculty, including positions of power such as departmental and institutional leadership. While the proportion of women among geoscience faculty has been catalogued previously, new programs and initiatives aimed at improving diversity, focused on institutional factors that affect equity in the geosciences, necessitate an updated study and a new metric for quantifying the biases that result in under-representation . We compile a dataset of 2,531 tenured and tenure-track geoscience faculty from 62 universities in the United States to evaluate the proportion of women by rank and discipline. We find that 27% of faculty are women. The fraction of women in the faculty pool decreases with rank, as women comprise 46% of assistant professors, 34% of associate professors, and 19% of full professors. We quantify the attrition of women in terms of a fractionation factor, which describes the rate of loss of women along the tenure track and allows us to move away from the metaphor of the ‘leaky pipeline’. Efforts to address inequities in institutional culture and biases in promotion and hiring practices over the past few years may provide insight into the recent positive shifts in fractionation factor. Our results suggest a need for 1:1 hiring between men and women to reach gender parity. Due to significant disparities in race, this work is most applicable to white women, and our use of the gender binary does not represent gender diversity in the geosciences.

Gas hydrates stored in the continental margins of the world’s oceans represent the largest global reservoirs of methane. Determining the source and history of methane from gas hydrate deposits informs the viability of sites as energy resources, and potential hazards from hydrate dissociation or intense methane degassing from ocean warming. Stable isotope ratios of methane (13C/12C, D/H) and the molecular ratio of methane over ethane plus propane (C1/C2+3) have traditionally been applied to infer methane sources, but often yield ambiguous results when two or more sources are mixed, or when compositions were altered by physical (e.g., diffusion) or microbial (e.g., methanotrophy) processes. We measured the abundance of clumped methane isotopologue (13CH3D) alongside 13C/12C and D/H of methane, and C1/C2+3 for 46 submarine gas hydrate specimens and associated vent gases from 11 regions of the world’s oceans. These samples are associated with different seafloor seepage features (oil seeps, pockmarks, mud volcanoes, and other cold seeps). The average apparent equilibration temperatures of methane from the Δ13CH3D (the excess abundance of 13CH3D relative to the stochastic distribution) geothermometer increase from cold seeps (15 to 65 ℃) and pockmarks (36 to 54 ℃), to oil-associated gas hydrates (48 to 120 ℃). These apparent temperatures are consistent with, or a few tens of degrees higher than, the temperature expected for putative microbial methane sources. Apparent methane generation depths were derived for cold seep, pockmark, and oil seep methane from isotopologue-based temperatures and the local geothermal gradients. Estimated methane generation depths ranged from 0.2 to 5.3 kmbsf, and are largely consistent with source rock information, and other chemical geothermometers based on clay mineralogy and fluid chemistry (e.g., Cl, B, and Li). Methane associated with mud volcanoes yielded a wide range of apparent temperatures (15 to 313℃). Gas hydrates from mud volcanoes the Kumano Basin and Mediterranean Sea yielded δ13C-CH4 values from -36.9 to -51.0‰, typical for thermogenic sources. Δ13CH3D values (3.8 to 6.0‰) from these sites, however, are consistent with prevailing microbial sources. These mud volcanoes are located at active convergent plate margins, where hydrogen may be supplied from basement rocks, and fuel methanogenesis to the point of substrate depletion. In contrast, gas hydrate from mud volcanoes located on km-thick sediments in tectonically less active or passive settings (Black Sea, North Atlantic) yielded microbial-like δ13C-CH4 and C1/C2+3 values, and low Δ13CH3D values (1.6 to 3.3‰), which may be due to kinetic isotope effects. This study is the first to document the link between methane isotopologue-based temperature estimates and key submarine gas hydrate seepage features, and validate previous models about their geologic driving forces.