Recent observations from the ExoMars Trace Gas Orbiter (TGO) have revealed the presence of hydrogen chloride (HCl) in the martian atmosphere. HCl shows strong seasonality, primarily appearing during Mars’ perihelion period and rapidly decreasing afterwards faster than projected from photolysis and gas-phase chemistry. HCl also shows anti-correlation with atmospheric water ice. One candidate explanation is heterogeneous chemistry. We present the first results from a heterogeneous chlorine chemistry scheme incorporated into a Mars global climate model (GCM), with atmospheric dust/water ice parameterized as an HCl source/sink respectively. Results were compared against a Mars GCM with gas-phase only chlorine chemistry and observations from TGO’s Atmospheric Chemistry Suite (ACS). We found that the heterogeneous scheme significantly improved the modelled HCl seasonal, latitudinal, and vertical distribution, supporting a crucial role for heterogeneous chemistry in Mars’ chlorine cycle. Remaining discrepancies show that further work is needed to characterise the exact aerosol reactions involved.

Super-rotation affects - and is affected by - the distribution of dust in the martian atmosphere. We modelled this interaction during the 2018 global dust storm (GDS) of Mars Year 34 using data assimilation. Super-rotation increased by a factor of two at the peak of the GDS, as compared to the same period in the previous year which did not feature a GDS. A strong westerly jet formed in the tropical lower atmosphere, with strong easterlies above 60 km, as a result of momentum transport by thermal tides. Enhanced super-rotation is shown to have commenced 40 sols before the onset of the GDS, due to equatorward advection of dust from southern mid-latitudes. The uniform distribution of dust in the tropics resulted in a symmetric Hadley cell with a tropical upwelling branch that could efficiently transport dust vertically; this may have significantly contributed to the rapid expansion of the storm.