Time-lapse borehole nuclear magnetic resonance (bNMR) relaxation is a promising method for linking water content changes in the unsaturated region of the critical zone with pore-scale properties associated with bedrock weathering. The saturation-dependance of the NMR T2 distribution is strongly controlled by pore-scale material properties and can be linked to hydraulic properties (e.g. the water retention function and hydraulic conductivity). Here, we leverage NMR’s sensitivity to pore-scale properties to investigate material controls on plant-available water storage dynamics in weathered bedrock via time-lapse bNMR relaxation measurements. To overcome slow logging speed and poor signal-to-noise (SNR) ratio typically associated with bNMR measurements in the unsaturated zone, we focus on the sum of echos (SE). We show that the advantage of using SE to characterize NMR relaxation, rather than using the full T2 distribution or the logarithmic mean of the distribution, is that it is easy to calculate, does not require inversion, has enhanced SNR, and is sensitive to both volumetric water content (VWC) and mean T2. This leads to high contrast in SE between time-lapse measurements relative to other metrics of NMR relaxation. At our hillslope study site associated with the Eel River CZO, VWC changes in weathered bedrock driven by deeply-rooted trees allow us to create “NMR characteristic curves” for different regions of the weathering profile. Analogous to a water retention function, the NMR characteristic curves describe NMR relaxation times of a material at a given VWC, and can be used to identify differences in pore-scale properties. We show that mean T2 times are typically shorter in bedrock that is more weathered for the same VWC, which is consistent with smaller pore-sizes and higher surface relaxivities associated with weathering products such as secondary clays and oxides. Our well logging indicates that changes in pore structure associated with bedrock weathering control plant-available water supply within the bedrock weathering profile. While these results illustrate the utility of bNMR, further studies that quantitatively link NMR measurements to flow properties via pore or empirical models will benefit mechanistic understanding of plant available water in the critical zone.