Mars’ dayside ionosphere is maintained primarily by ionization from solar ultraviolet photons and subsequent chemical reactions, with small contributions from other mechanisms such as impact ionization and charge exchange. In December 2023, the Mars Atmosphere and Volatile EvolutioN (MAVEN) mission observed the impact of an interplanetary coronal mass ejection (ICME) on Mars’ ionosphere, including strongly enhanced fluxes of suprathermal electrons. We show that this enhancement in suprathermal electron fluxes increased ion production from electron impact, so that dayside electron impact ionization rates exceeded photoionization rates during the ICME. This change in ion production mechanisms led to unusually high densities of the minor ions C+ and O++. Space weather events are known to increase ion escape rates, so changes in ion composition during space weather events have important implications for atmospheric evolution. We show that scaling nominal loss rates to account for space weather may underestimate carbon loss from Mars’ atmosphere.

In situ measurements of ionospheric and thermospheric temperatures are experimentally challenging because orbiting spacecraft typically travel supersonically with respect to the cold gas and plasma. We present O2+ temperatures in Mars’ ionosphere derived from data measured by the SupraThermal And Thermal Ion Composition (STATIC) instrument onboard the Mars Atmosphere and Volatile EvolutioN (MAVEN) spacecraft. We focus on data obtained during nine special orbit maneuvers known as Deep Dips, during which MAVEN lowered its periapsis altitude from the nominal 150 km to 120 km for one week in order to sample the ionospheric main peak and approach the homopause. We use two independent techniques to calculate ion temperatures from the measured energy and angular widths of the supersonic ram ion beam. After correcting for background and instrument response, we are able to measure ion temperatures as low as 100 K with associated uncertainties as low as 10%. It is theoretically expected that ion and electron temperatures will converge to the neutral temperature at altitudes below the exobase region (~180-200 km) due to strong collisional coupling; however, no evidence of the expected thermalization is observed. We have eliminated several possible explanations for the observed temperature difference between ions and neutrals, including Coulomb collisions with electrons, Joule heating, and heating caused by interactions with the spacecraft. Our current study leaves one plausible heating mechanism, the release of internal energy from O2+ that becomes vibrationally excited as a result of atmospheric chemistry, but future work is needed to assess its validity.