The conditions in Venus’ upper mesosphere at around 120 km have some similarities to the upper mesosphere of Earth and Mars where ice clouds form. Here we show, using published satellite products and numerical modelling, that the upper mesosphere of Venus is sufficiently cold that both H2O and CO2 can condense to form particles. In fact, we show that there is likely to be a competition between the direct nucleation of particles from the gas phase (homogeneous nucleation) and the nucleation on meteoric smoke particles (MSPs, heterogeneous nucleation). Amorphous solid water particles (ASW) are likely to nucleate first, resulting in clouds of nano-scaled particles at around 120 km globally. The temperatures can then become sufficiently low that CO2 particles can nucleate either on MSPs or on ASW particles (>30% of the time poleward of 60°). Since the main component of the atmosphere is CO2 these particles will grow and sediment on a timescale of 10-20 minutes. Mie calculations show that these Venusian mesospheric clouds (VMCs) should be observable by contemporary satellite instruments, although their short lifetime means that the probability of detection is small. We suggest that VMCs are important for the redistribution of meteoric smoke and may serve as a cold-trap, removing some water vapour from the very upper mesosphere of Venus, through the growth and sedimentation of cloud particles, and possibly reducing the loss of water to space.

Water ice clouds form in the mesospheres of terrestrial planets in the solar system (and most likely elsewhere) by vapor deposition at low pressures and temperatures. Under these conditions a range of crystalline and amorphous phases of ice might form. The phase is important because it influences nucleation kinetics, density, vapor pressure over the solid, growth rates and particle shape. In the past the temperature range over which these different phases exist has been defined on the basis of depositing ice at low temperature and warming it while observing phase changes. However, the direct deposition of ice at a range of temperatures relevant for the terrestrial planets has not been systematically investigated. Here we present X-ray Diffraction (XRD) measurements of water ice deposited at temperature intervals between 88 and 145 K in a vacuum chamber. XRD patterns showed that low density amorphous ice was formed at ≤ 120 K, stacking disordered ice I formed from 121 – 135 K and hexagonal ice I formed at 140 and 145 K. Direct deposition results in the stable hexagonal phase at much lower temperatures than when warming stacking disordered ice. All three phases of water ice observed here are possible in clouds in the mesospheres of Earth and Mars, while on Venus only amorphous ice is likely to form.

Poor understanding of aerosol-cloud interactions and cloud feedback processes in the Arctic climate system limit our ability to constrain future climate in the region and one important knowledge gap is the source of particles upon which cloud droplets and ice crystals have formed. If representative cloud-water can be obtained from Arctic clouds, it’s chemical composition can be analysed to infer the sources of particles present within it. However, the balloon-borne active cloud water sampling systems required to obtain such samples have not previously been feasible due to their weight and the challenging environmental conditions. Here we present a miniaturised cloud-water sampler for balloon-borne collection of cloud water which was deployed during the Microbiology-Ocean-Cloud-Coupling in the High Arctic (MOCCHA) campaign in August and September 2018 along with the deployment protocol required to obtain representative samples in the pristine conditions encountered. We present the chemical composition of the samples obtained as well as the ice-nucleating activity of the samples and discuss the implications of our results on aerosol-cloud interactions in the high Arctic.

The amount of ice versus supercooled water in clouds defines their radiative properties and role in climate feedbacks. Hence, knowledge of the concentration of ice-nucleating particles (INPs) is needed. Generally, the concentrations of INP is found to be very low in remote marine locations allowing clouds to persist in a supercooled state. However, little is known about the INP population in clouds at and around the summertime North Pole. We had expected that concentrations of INPs at the North Pole would have been very low given the distance from open ocean and terrestrial sources coupled with effective wet scavenging processes. Here we show that during summer 2018 (August and September) high concentrations of biological INPs (active at >-20°C) were present at the North Pole. In fact, INP concentrations were sometimes as high as those recorded in mid-latitude locations strongly impacted by highly active biological INPs, in strong contrast to the Southern Ocean. Furthermore, using a balloon borne sampler we demonstrated that INP concentrations were often different at the surface versus higher in the boundary layer where clouds form. Back trajectory analysis suggests that there were strong sources of INPs near the Russian coast, possibly associated with wind-driven sea spray production, whereas the pack ice, open leads, and the marginal ice zone were not sources of highly active INPs. These findings suggest that primary ice production, and therefore Arctic climate, is sensitive to transport from locations such as the Russian coast that are already experiencing marked climate change.

We have developed a new experimental system to study the pyrolysis of the refractory organic constituents in cosmic dust. Pyrolysis is observed by mass spectrometric detection of CO2 and SO2, and starts from around 850 K. The time-resolved kinetic behaviour is consistent with two organic components – one significantly more refractory than the other, which probably correspond to the insoluble and soluble organic fractions, respectively. The laboratory results are then incorporated into the Leeds Chemical Ablation Model (CABMOD), which is used to predict the conditions under which organic pyrolysis should be detectable using a high performance/large aperture radar. It has been proposed that loss of the organics leads to fragmentation of cometary dust particles into micron-sized fragments. If fragmentation of dust particles from Jupiter Family and Halley Type Comets does occur to a significant extent, there are several important implications: 1) slow-moving particles, particularly from Jupiter Family Comets, will be undetectable by radar, so that the total dust input to the atmosphere may be considerably larger than current estimates of 20 – 50 tonnes per day; 2) experiments at Leeds show that meteoritic fragments are excellent ice nuclei for freezing stratospheric droplets in the polar lower stratosphere, producing polar stratospheric clouds which activate chlorine and cause ozone depletion; and 3) the measured accumulation rates of meteoric smoke particles, micrometeorites and cosmic spherules in the polar regions can now be explained self-consistently.