Albrecht W. Hofmann

and 2 more

Most efforts to characterize the size and composition of the mantle that complements the continental crust have assumed that the mid-ocean ridge basalt (MORB) source is the incompatible-element depleted residue of continental crust extraction. The use of Nd isotopes to model this process led to the conclusion that the “depleted MORB reservoir” is confined to the upper ~30% of the mantle, leaving the lower mantle in a more “primitive” state. Here we use Nb/U and Ta/U to evaluate mass and composition of the mantle reservoir residual to continent extraction and find that it exceeds 67% of the total mantle. Thus the (Nb,Ta)/U-based mass balance conflicts with the ε(Nd)-based mass balance, and this invalidates the classical 3-reservoir silicate Earth model (continental crust, depleted mantle, primitive mantle). Including the combined MORB + ocean island basalt (OIB) sources in the ε(Nd)-based mass balance does not reconcile the conflict as it would require their average ε(Nd) to be ≤3.0, much lower than observed MORB+OIB ε(Nd) averages. We resolve this conflict by invoking an additional, “early-enriched reservoir” (EER), formed prior to extraction of significant continental crust, but now hidden or lost. This EER differs from EERs previously invoked by having no Nb-Ta anomaly. We suggest that it originated as an early mafic crust, which had unfractionated (Nb,Ta)/U but fractionated Sm/Nd ratios. The corresponding “early-depleted” reservoir (EDR) generated the present-day continental crust and the “residual mantle” MORB-OIB reservoir, which occupies at least 70% of the present-day mantle and is only moderately depleted in incompatible trace elements.

Albrecht W. Hofmann

and 2 more

Most previous efforts to characterize the size and composition of the upper mantle, the source of mid-ocean ridge basalts (MORBs), have assumed that this MORB source is the residue of continental crust extraction. The use of Nd isotopes to model this process led to the near-consensus that the “depleted MORB reservoir” is more-or-less confined to the upper mantle (above 670 km, ~30% of the mantle), with a severe degree of depletion of incompatible elements, leaving the lower mantle in a more primitive state. Here, we reassess the mass and composition of the mantle reservoir depleted by continental crust extraction. We initially apply simple mass balance considerations, using alternatively ε(Nd) and “canonical” (Nb,Ta)/U tracers, to a conventional three-reservoir silicate Earth consisting of primitive mantle, continental crust, and depleted mantle. The (Nb,Ta)/U tracer yields a ‘depleted reservoir’ exceeding 60% by mass of the total mantle (X(DM) > 0.6) with average ε(Nd) ≤ 3, whereas the ε(Nd)-based mass balance, using ε(Nd) = 8.5, yields a “depleted reservoir” of X(DM) ≤ 0.3. This discrepancy requires additional processes/reservoirs that impact the fractionation of Sm/Nd in the depleted mantle. Simple segregation of enriched OIB sources is shown to be insufficient. Permanent sequestration of a fourth, early-enriched, mafic reservoir (EER), leaving behind an early-depleted reservoir (EDR) can resolve the dilemma. Segregation of the present-day continental crust from EDR generates a moderately depleted, “residual-mantle” reservoir (RM), which occupies 80-98% of the total mantle (X(RM) = 0.8-0.98). This leads to concordant results for the two crust-mantle mass balances.