A document by Grant Ferguson. Click on the document to view its contents.

Deep incised glacial valleys surrounded by high peaks form the modern topography of the Southern Patagonian Andes. Two Miocene plutonic complexes in the Andean retroarc, the cores of the Fitz Roy (49°S) and Torres del Paine (51°S) massifs, were emplaced at 16.7±0.3 Ma and 12.5±0.1 Ma, respectively. Subduction of ocean ridge segments initiated at 54°S, generating northward opening of an asthenospheric window with associated mantle upwelling and orogenic shortening since 16 Ma. Subsequently, the onset of major glaciations at 7 Ma caused drastic changes in the regional topographic evolution. To constrain the respective contributions of tectonic convergence, mantle upwelling and fluvio-glacial erosion to rock exhumation, we present inverse thermal modeling of a new dataset of zircon and apatite (U-Th)/He from the two massifs, complemented by apatite 4He/3He data for Torres del Paine. Our results show rapid rock exhumation recorded in the Fitz Roy massif between 10.5 and 9 Ma, which we ascribe to mantle upwelling and/or crustal shortening due to ridge subduction at 49°S. Both massifs record a pulse of rock exhumation between 6.5 and 4.5 Ma, which we interpret as the result of the onset of Patagonian glaciations. After a period of erosional quiescence during the Miocene/Pliocene transition, increased rock exhumation since 3-2 Ma to present day is interpreted as the result of alpine glacial valley carving promoted by reinforced glacial-interglacial cycles. This study demonstrates that along-strike thermochronological studies provide us with the means to assess the spatio-temporal variations in tectonic, mantle, and surface processes forcing on rock exhumation.

Cenozoic growth of the Andes has been strongly influenced by subduction dynamics, reactivation of inherited crustal heterogeneities, and the superposed effects of climate. Subduction of the submarine Carnegie Ridge has fundamentally impacted late Cenozoic magmatism and tectonic activity in the northern Andes. Time-temperature inverse modeling of new thermochronological data from the Western Cordillera of Ecuador reveals two phases of cooling separated by isothermal conditions. The first cooling phase immediately postdates early and middle Miocene magmatism in the Western Cordillera and is attributed to post-magmatic thermal relaxation. The second cooling phase started after 6 Ma, which we infer to record the exhumation in the Western Cordillera, coeval with the last cooling phase in the Eastern Cordillera. Based on these findings we posit that the onset of subduction of the Carnegie Ridge at ~6-5 Ma increased plate coupling at the subduction interface and promoted shortening and regional rock uplift in the northern Andes. Overall, our results highlight the essential role of bathymetric anomalies in driving regional upper-plate deformation at non-collisional convergent plate margins.

Extensive regions of yellow and white (‘bleached’) sandstones within the terrestrial Jurassic red bed deposits of the Colorado Plateau reflect widespread interaction with subsurface reduced fluids which resulted in the dissolution of iron-oxide grain coatings. Reduced fluids such as hydrocarbons, CO2, and organic acids have been proposed as bleaching agents. In this study, we characterize an altered section of the Slick Rock member of the Jurassic Entrada Sandstone that exposes bleached sandstone with bitumen-saturated pore spaces. We observe differences in texture, porosity, mineralogy, and geochemistry between red, pink, yellow, and gray facies. In the bleached yellow facies we observe quartz overgrowths, partially dissolved K-feldspar, calcite cement, fine-grained illite, TiO2-minerals, and pyrite concretions. Clay mineral content is highest at the margins of the bleached section. Fe2O3 concentrations are reduced up to 3x from the red to gray facies but enriched up to 50x in iron-oxide concretions. Metals such as Zn, Pb, and rare-earth elements are significantly enriched in the concretions. Supported by a batch geochemical model, we conclude the interaction of red sandstones with reduced hydrocarbon-bearing fluids caused iron-oxide and K-feldspar dissolution, and precipitation of quartz, calcite, clay, and pyrite. Localized redistribution of iron into concretions can account for most of the iron removed during bleaching. Pyrite and carbonate stable isotopic data suggest the hydrocarbons were sourced from the Pennsylvanian Paradox Formation. Bitumen in pore spaces and pyrite precipitation formed a reductant trap required to produce Cu, U, and V enrichment in all altered facies by younger, oxidized saline brines.

Krypton-81 dating provides new insights into the timing, mechanisms, and extent of meteoric flushing versus retention of saline fluids in the subsurface in response to changes in geologic and/or climatic forcings over 50 ka to 1.2 Ma year timescales. Remnant Paleozoic seawater-derived brines (2-2.5 km depth) associated with evaporites in the Paradox Basin, Colorado Plateau, are beyond the 81Kr dating range (>1.2 Ma) and have likely been preserved due to negative fluid buoyancy and low permeability. 81Kr dating of formation waters above the evaporites indicates topographically-driven meteoric recharge (0.03-0.8 Ma) and salt dissolution since the Late Pleistocene. Formation waters below the evaporites, in basal aquifers, contain relatively young meteoric water components (0.4-1.1 Ma based on 81Kr) that partially flushed remnant brines and dissolved evaporites. We demonstrate that recent, rapid denudation of the Colorado Plateau (<4-10 Ma) activated deep, basinal-scale flow systems as recorded in 81Kr groundwater age distributions.