The SuperCam instrument onboard Perseverance rover has remote imaging (RMI), VISIR, LIBS, Raman and Time-Resolved Luminescence (TRL) capabilities. RMI images of the rocks at the Octavia Butler landing site have revealed important granular texture diversities. VISIR raster point observations have revealed important differences in the 2.10-2.50 µm infrared range (metal-hydroxides); many include water features at 1.40±0.04 and 1.92±0.02 µm [1]. LIBS observations on the same points analyzed by VISIR revealed important differences in the concentrations of major elements, suggesting mineral grain sizes larger than the laser beam (300-500 µm). LIBS and VISIR show coherent results in some rock surfaces that are consistent with an oxy-hydroxide (e.g., ferrihydrite) [1]. LIBS elemental compositions are consistent with pyroxenes, feldspars, and more often feldspar-like glass, often enriched in silica. Olivine compositions [1, 2] have been observed so far in LIBS data (up to Sol 140) exclusively in rounded regolith pebbles. They have not yet been observed in the rocks themselves, which are MgO-poor compared to regolith and are consistent with FeO bearing pyroxenes (e.g., hedenbergite, ferrosilite). A 3x3 LIBS and VISIR raster (9x9 mm) acquired on a low-standing rock on sol 90 exemplifies these finding. A dark L-shaped filled void sampled by points 1 and 2 with possible ferrihydrite (H seen in LIBS and VISIR spectra). Point 5 contains abundant silica and alkali elements but is Al-depleted relative to feldspars, consistent with dacitic glass composition. Point 7 has TiO2 content consistent with ilmenite. Comparisons to (igneous) Martian meteorites are potentially useful, e.g. [3], to explain the presence of several minerals, although most Martian meteorites are olivine-rich, e.g., more mafic than the rocks at the landing site. In summary, the bedrock at Octavia Butler landing site can be interpreted as showing evidence for relatively coarse-grained weathered pyroxenes, iron and titanium oxides and feldspars, while the local soil contains pebbles from a different source (richer in MgO) incorporating olivine grains. References: [1] Mandon et al. 2021 Fall AGU, New Orleans, LA, 13-17 Dec. ; [2] Beyssac et al. 2021 Fall AGU, New Orleans, LA, 13-17 Dec. ; [3] Garcia-Florentino et al.(2021), Talanta, 224, 121863.

The NASA Mars 2020 Perseverance rover mission will collect a suite of scientifically compelling samples for return to Earth. On the basis of orbital data, the Mars 2020 science team* identified two notional sample caches to study (1) the geology of Jezero crater, collected during the prime mission and (2) the ancient crust outside of Jezero crater, collected during a possible extended mission. Jezero crater geology consists of well-preserved, Early Hesperian to Late Noachian deltaic and lacustrine deposits sourced from a river system that drained Noachian terrain. The crater floor comprises at least two distinct units of sedimentary or volcanic origin whose relationship to the deltaic deposits is presently unclear. Remotely-sensed data reveal signatures of carbonate+olivine and clay minerals within crater floor and crater margin units. Samples from within Jezero that comprise the prime mission notional sample collection thus include: crater floor units; fine- and coarse-grained delta facies, the former with potential to preserve organic matter and/or biosignatures, the latter to possibly constrain the type and timing of sediment deposition; chemical sediments with the potential to preserve biosignatures; a sample of crater rim bedrock; and at least one sample of regolith. The region of southern Nili Planum, directly outside the western rim of Jezero crater, is geologically distinct from Jezero crater and contains diverse Early or even Pre-Noachian lithologies, that may contain records of early planetary differentiation, magnetism, paleoclimate and habitability. The notional sample collection from this region will include: layered and other basement rocks; megabreccias, which may represent blocks of (pre-)Noachian crust; basement-hosted hydrothermal fracture fill; olivine+carbonate rocks that are regionally significant and may be related to units within Jezero crater; and mafic cap unit rocks. The samples described are notional and may change with ongoing surface investigations. However, the samples we anticipate collecting align well with community priorities for Mars exploration, addressing geologic diversity, potential ancient biologic activity on Mars, planetary evolution, volatiles, and human health hazards. *Many other Mars 2020 team members were involved in this planning