Abstract
Agricultural emissions of ammonia (NH3) impact air quality, human
health, and the vitality of aquatic and terrestrial ecosystems. In the
UK, there are few direct policies regulating anthropogenic NH3 emissions
and development of sustainable mitigation measures necessitates reliable
emissions estimates. Here we use observations of column densities of NH3
from two space-based sensors (IASI and CrIS) with the GEOS-Chem model to
derive top-down NH3 emissions for the UK at fine spatial
(~10 km) and time (monthly) scales. We focus on
March-September when there is adequate spectral signal to reliably
retrieve NH3. We estimate total emissions of 272 Gg from IASI and 389 Gg
from CrIS. Bottom-up emissions are 27% less than IASI and 49% less
than CrIS. There are also differences in seasonality. Top-down and
bottom-up emissions agree on a spring April peak due to fertilizer and
manure application, but there is also a comparable summer July peak in
the top-down emissions that is not in the bottom-up emissions and
appears to be associated with dairy cattle farming. We estimate relative
errors in the top-down emissions of 11-36% for IASI and 9-27% for
CrIS, dominated by column density retrieval errors. The bottom-up versus
top-down emissions discrepancies estimated in this work impact model
predictions of the environmental damage caused by NH3 emissions and
warrant further investigation.