javascript:void(0) In the international photovoltaic market, the "carbon footprint" label has received great attention, and low-carbon footprint products are widely popular. Compared with metallic silver, copper has the characteristics of low carbon emissions and low cost, which can effectively reduce the carbon footprint. Based on this, this article reports a horizontal double-sided Copper metallisation technology. This technology can not only metallize the front and back sides of various types of silicon solar cells at the same time, but also has fast speed, good uniformity, and simple process, making it suitable for the industrial mass production of solar cells. This article describes the structure and manufacturing process of TOPCon solar cells patterned with ultrashort pulse laser and metallized using this novel horizontal double-sided copper metallisation technology. In this batch, average efficiency reached above 26%.

It is common practice in PV system simulation to use the De Soto model, which describes how to use the 1-diode equivalent circuit model for modules. De Soto’s model scales the shunt with irradiance, making it disappear towards zero W/m 2. Also, the commercial software PVsyst uses a parameterization that reduces the shunt effect when the irradiance goes down. However, the Si solar cells that make up a module typically do not have an illumination dependent shunt. We therefore investigate the origin of the intensity dependent apparent shunt in modules. We show that this apparent shunt (derived from the slope of the quasi-linear region from I SC onwards) is a misinterpretation and has little to do with a shunt conductance. Instead, the module I- V curve slope of the quasi-linear region from I SC onwards stems from I SC mismatches between the cells. Such mismatch can occur from small illumination inhomogeneity or cell production variation. Abandoning the practice of using the I- V curve slope to determine the shunt value for equivalent circuit models of modules (and the corresponding shunt scaling in the De Soto model or PVsyst), contributes to physically more meaningful I- V curve parameterizations and possibly also more accurate PV system energy yield prediction.

Tunnel oxide passivated contact TOPCon is poised to emerge as the predominant technology in photovoltaic (PV) cells, yet significant reliability issues remain unresolved. This study conducts a comparative analysis of 20 TOPCon PV module types, utilizing a range of electrical characterization and accelerated aging assessments. This investigation provides a detailed evaluation of the electrical performance, resulting in an Energy Rating of the modules, establishing a benchmark for cutting-edge TOPCon technology. While some failure modes, such as LeTID, appear to be non-critical, the findings confirm previously identified degradation pathways in TOPCon modules due to moisture penetration. During UV exposure, a novel degradation pattern was observed during the indoor tests, showing severe losses (up to -12% after 120 kWh/m 2), followed by recovery after humidity freeze-testing, which may influence outdoor performance and the outcomes of certification tests (IEC61730-2, Sequence B). The results highlight the areas of need for more targeted testing and technological refinement.

A simple binary antimony selenide (Sb 2Se 3) absorber is evolving as an alternative photovoltaic material in thin film solar cells because of its unique properties and easy processing. Sb 2Se 3 thin films having good crystalline quality are grown via versatile thermal evaporation from pre-synthesized near stoichiometric compound material on molybdenum coated soda lime glass (SLG) and borosilicate glass (BG) substrates. Following the systematic characterizations on the absorber films, substrate configured Sb 2Se 3/CdS heterojunction devices were fabricated and their photovoltaic characteristics have been studied using current density vs voltage (J-V), dark J-V modelling, external quantum efficiency, capacitance vs voltage measurements. The power conservation efficiency values of 4.88 % and 5.04 % were achieved for the devices fabricated on SLG and BG, respectively. The obtained values are higher in comparison to the reported device efficiencies in substrate configured Sb 2Se 3 solar cells, in which the absorber is prepared through thermal evaporation. To understand the loss in open circuit voltage , a compact equivalent circuit model was considered to identify the shunt leakage pathways. In addition to that the device fabricated on the SLG were structurally stable with minimal changes in its performance for a period spanning over 200 days. The results obtained are encouraging with scope for improving the device performance through interface engineering and back surface passivation strategies.

The IEC 61853 standard series define the Climate Specific Energy Rating (CSER) which can be used within the Photovoltaic (PV) community as a reliable and accurate tool to predict a PV module’s energy output for specific climate and allows to differentiate between PV modules according to their specific performance for representative locations. The CSER power rating parameter is assumed to represent the PV device performance in real-world operation. So far, research has mainly focused on the implementation of different algorithms to determine the input parameters and to calculate the CSER values based on indoor measurement performance rating data. There is lack of information and technical specification how to obtain these parameters from outdoor field operating PV module data that reflects better the module performance behaviour. In the present study, we analysed long-term outdoor field data for a period of 36 consecutive months of a PV module in order to understand how the length (and seasonality) of the data acquisition period impacts the reliability of irradiance and temperature power matrix values, particularly in relation to CSER calculations. The PV outdoor performance data has been validated against its indoor counterpart. The results concluded that a period of 9 or 12 months provides a good compromise between accuracy and time-resources. This may be reduced to 6-month provided the meteorological conditions are sufficiently diverse in this time frame. The study provides important insights to the PV community since the CSER parameter may become a compulsory requirement for each PV module produced, imported or sold in Europe if the potential EU Ecodesign Directive and the Energy Labelling Regulation will be implemented.

Daylight photoluminescence imaging of crystalline silicon photovoltaic modules is demonstrated for modules embedded in rooftop and utility-scale systems, using inverters to electrically switch the operating point of the array. The method enables rapid and high-quality luminescence image acquisition during the day, unlocking efficient performance and quality monitoring without the need to connect specific electrical hardware or to make any modifications to the system wiring. The principle of the measurement approach is discussed and experimental results from a 10 kW DC residential rooftop system and from a 149 MW DC utility-scale photovoltaic power plant are presented. Measurements were performed using commercial inverters without modifications to the inverter hardware or firmware. In the case of the utility-scale power plant, the daylight photoluminescence image acquisition of modules connected to a central inverter was obtained from a remote piloted aircraft. Data analysis includes the conversion of photoluminescence image data into implied voltage differences.

This study presents a comprehensive multidisciplinary review of autonomous monitoring and analysis of large-scale photovoltaic (PV) power plants using enabling technologies, namely artificial intelligence, machine learning, deep learning, internet of things, unmanned aerial vehicle, and big data analytics, aiming to automate the entire condition monitoring procedures of PV systems. Autonomous monitoring and analysis is a novel concept for integrating various techniques, devices, systems, and platforms to further enhance the accuracy of PV monitoring, thereby improving the performance, reliability, and service life of PV systems. This review article covers current trends, recent research paths and developments and future perspectives of autonomous monitoring and analysis for PV power plants. Additionally, this study identifies the main barriers and research routes for the autonomous and smart condition monitoring of PV systems, to address the current and future challenges of enabling the PV terawatt transition. The holistic review of the literature shows that the field of autonomous monitoring and analysis of PV plants is rapidly growing and is capable to significantly improve the efficiency and reliability of PV systems. It can also have significant benefits for PV plant operators and maintenance staff, such as reducing the downtime and the need for human operators in maintenance tasks, as well as increasing the generated energy.

Levelized cost of electricity (LCOE) is a crucial metric for assessing the socio-economic cost-efficiency potential of various energy sources including solar photovoltaics. Nevertheless, accurate LCOE estimations for commercialized high-efficiency Si solar modules with passivated emitter and rear cell (PERC) and silicon heterojunction (SHJ) structures have been lacking. In this study, we present the first global LCOE estimates for a PERC module (20% cell efficiency) and a SHJ module (23% cell efficiency), which have been derived by (i) performing rigorous energy-yield calculations with full-spectral and temperature-dependent simulations that incorporate all essential meteorological effects and (ii) considering country-specific capital costs and discount rates. Moreover, to determine the universal global LCOE, the LCOEs for three distinct installation capacities (100 MW for a utility, 500 kW for a commercial, and 5 kW for a residential system) have been unified by selecting an appropriate system size at each location based on a population density. We find that the LCOEs of both PERC and SHJ systems are below 3 cent/kWh in 2020 US dollar in many areas of China, Saudi Arabia, the United States, Australia, Chile, and Botswana where the conditions of a high energy yield, low population density, low capital cost, and low country-risk premium are satisfied simultaneously. In contrast, many European countries exhibit a moderate LCOE of 3~5 cent/kWh. Notably, Japan and Russia exhibit quite high LCOEs (6~10 cent/kWh) primarily due to significantly higher installation costs and moderate energy yields. Importantly, the global LCOEs of the PERC and SHJ modules are quite similar, with the SHJ module showing a slightly better cost performance in the regions near equator due to its low temperature coefficient. Conversely, the PERC module demonstrates cost advantage in the northern hemisphere due to a lower module cost.

As the efficiency of perovskite silicon tandem solar cells is increasing, the upscaling for industrial production is coming into focus. Spatially resolved, quantitative, fast, and reliable contactless measurement techniques are demanded for quality assurance and to pinpoint the cause of performance losses in perovskite silicon tandem solar cells. In this publication we present a measurement method based on spectrally integrated photoluminescence (PL) imaging to extract subcell-selective implied open-circuit ( i V oc ) images from monolithic perovskite silicon tandem solar cells. We validate the approach using spectrally resolved absolute PL measurements based on an integrating sphere for the perovskite top cell and PL-calibrated carrier lifetime images for the silicon bottom cell. Additionally, V oc measurements of solar cells with low contact losses are used to validate the new measurement technique. We find a good agreement of the i V oc images with the validating measurements with a maximum deviation of well below 1 % compared to the validation measurements.

This paper provides a comprehensive assessment of the up-to-date life-cycle sustainability status of cadmium-telluride based photovoltaic (PV) systems. Current production modules (Series 6 and Series 7) are analyzed in terms of their energy performance and environmental footprint and compared with the older series 4 module production and current single-crystalline-silicon (sc-Si) module production. For fixed-tilt systems with series 6 modules operating under average US irradiation of 1800 kWh/m 2/yr, the global warming potential (GWP) is reduced from 16 g CO2 eq/kWh in Series 4 systems to 10 CO2 eq/kWh in Series 6 systems. For operation in US-SW irradiation of 2300 kWh/m2 the GWP is reduced from 11 CO2eq/kWh to 8 CO2eq/kWh and for 1-axis tracking systems operating in Phoenix, Arizona with point-of array irradiation of 3051 kWh/m 2/yr the GWP is reduced to 6.5 CO2 eq/kWh. Similar reductions have happened in all environmental indicators. Energy payback times (EPBT) of currently installed systems range from 0.6 years for fixed-tilt ground-mounted installations at average U.S. irradiation at latitude tilt installations, to 0.3 years for one-axis trackers at high US-SW irradiation, considering average fossil-fuel dominated electricity grids with fuel to electricity conversion efficiency of 0.3. The resulting energy return on energy investment (EROI) also depends on the conversion efficiency of the electricity grid and on the operation life expectance. For a 30-year operational life and grid conversion efficiency of 0.3, EROI ranges from 50 (at US average irradiation) to 70 for US-SW irradiation. The EROI declines with increased grid conversion efficiency; for CdTe PV operating in south California with grid conversion efficiency of 49% the EROI is about 50 and is projected to fall to 30 when the state’s 2030 target of 80% renewable energy penetration materializes. Material alternatives that show a potential of further reductions in degradation rates and materials for enhanced encapsulation that would enable longer operation lives are also been investigated. A degradation rate of 0.3%/year, which has been verified by accelerated testing, is assumed in 30-year scenarios; this is projected to be reduced to 0.2%/yr in the near-term and potentially to 0.1%/yr in the longer term. With such low degradation rates and enhanced edge-sealing, modules can last 40- to 50-years. Consequently, all impact indicators will be proportionally reduced while EROI will increase.

Increased deployment of solar PV enables the transition to decarbonized energy systems, capable of tempering the dire consequences of global warming. Even though backsheets are very important regarding lifetime energy yield of the PV module, the environmental impacts of their production, use and end-of-life (EoL) processing are largely neglected. As part of a recently finalized Dutch national project EXTENSIBLE (Energy yield assessment of neXT gENeration and SustaInaBLE backsheets) the environmental impacts for 7 different polymeric backsheets have been evaluated via a life cycle assessment (LCA). The selected backsheets include 3 traditional polyethylene terephthalate (PET) - based backsheets with a fluorine containing outer layer (two white pigmented and one fully transparent). The other 4 backsheets are novel high-performance polyolefin (PO) -based backsheets, manufactured by Endurans Solar ™, also including one transparent version. From results of the LCA it is concluded that in comparison with PET-based backsheets and fluoropolymer containing backsheets, PO-based backsheets perform best in terms of energy yield, reliability and environmental impacts. The production of fluoropolymer- and PET-based backsheets cause substantial environmental impacts, especially regarding climate change and ozone depletion. This conclusion is corroborated by recent literature data. Regarding the EoL phase, it was shown from a theoretical assessment that pyrolysis of the spent backsheets potentially leads to much lower GWP when compared to incineration, especially for the PO-based backsheets. Incineration of the shredded and solid backsheet material causes direct emissions of CO 2 with a limited heat recovery potential only. Deploying pyrolysis for spent PO-based backsheets significantly improves their life-time GWP per kWh produced. Pyrolysis offers the possibility to recover a large part of the polyolefin as an usable pyrolysis oil that might serve as feedstock for chemicals or as transportable liquid fuel for the generation of process heat in recovery boilers, thereby avoiding the use of new fossil resources. EoL pyrolysis (or incineration) of fluoropolymer-based backsheets is problematic due to the presence of fluorinated hydrocarbons, leading to corrosive and/or toxic products.

Efficient metal contact formation is pivotal for the production of cost-effective, high-performance crystalline silicon (Si) solar cells. Traditionally, screen-printed silver (Ag) contacts on the front surface have dominated the industry, owing to their simplicity, high throughput, and significant electrical benefits. However, the high cost associated with using over 13-20mg/Wp of Ag can impede the development of truly cost-effective solar cells. Therefore, there is an urgent need to explore alternative, economically viable metals compatible with silicon substrates. This study reports on the application of a contact stack consisting of Ag, nickel (Ni), and copper (Cu) in Si solar cells. To prevent Schottky contact formation, Ag is implemented as a seed layer, while Ni and Cu form the metal bulk layer. The fabricated bi-layer stack without selective emitter exhibits a maximum efficiency of ~21.5%, a fill factor of 81.5%, and an average contact resistance of 5.88mΩ·cm 2 for a monofacial PERC cell. Microstructure analysis demonstrate that the metals within the contacts remain distinct, and Cu diffusion into the silicon during the firing process is absent. Consequently, printed bi-layer contacts emerge as a promising alternative to Ag contacts, reducing the Ag consumption to below 2.5mg/Wp per cell without compromising overall efficiency.

Compound/silicon heterojunction (SCH) solar cells have been widely studied due to the low parasitic absorption of the window layer, high short-circuit current, and simple preparation process. So far, most reported SCH solar cells are small-area devices. By depositing MoO x hole transport layer using hot-wire oxidation-sublimation deposition technique and employing a front-contact back-junction cell architecture, the large-area SCH solar cells are successfully fabricated on M6 (166 mm) n-type silicon wafers. Indium cerium oxide (ICO) film with the optimal thickness of about 110 nm is inserted between MoO x and Ag. The ICO/Ag stack functions well as a back reflector and is beneficial for increasing the short-circuit current density, reducing the contact resistance, and improving the device stability. A power conversion efficiency of 21.59% is achieved on the champion SCH solar cell with the device area of 274.15 cm 2.

High levels of airborne dust, frequent dust storms and infrequent rain events are some of the reasons why soiling can drastically reduce the energy yield of photovoltaic modules in desert areas. There are ongoing and increasing efforts to identify appropriate and economically feasible strategies that can be used to mitigate soiling in deserts. Both innovative tracking with adapted resting positions during night and anti-soiling coatings (ASC) are considered as potential solutions to reduce soiling. In this study, the individual mitigation potential of both ASC and tracking routines as well as the combination of the two approaches are investigated. For this, outdoor exposure tests were carried out in desert region of Saudi Arabia. Coated and uncoated glass samples were tested in different tilt configurations: fixed, 1-axis tracking with horizontal stowage (facing the sky) and 1-axis tracking with vertical stowage during the night. Both methods indicate significant soiling reductions, especially for the combined solution of ASC and tracking with vertical night stowage, where soiling losses can be reduced by up to 85%. In addition, it has been shown that by adapting tracking, the relative ASC performance can be improved compared to fixed tilt or standard 1-axis tracking scenarios.

Organic photovoltaics (OPV) has attracted tremendous attention as a promising alternative to silicon wafer-based technologies for building integration. While significant progress has been achieved on the power conversion efficiency of OPV technologies, their field stability is rarely studied. This work investigates the field performance and reliability of a large-area OPV module designed for BIPV application in the tropical region of Singapore for 4.5 years. The device suffered more than 14% degradation in power at the standard testing conditions from the initial performance, largely due to losses in fill factor (-12% relative). During the monitoring period, it exhibited comparable performance to more conventional silicon PV technologies, with an average specific energy yield of about 4 kWh/kWp/day and an average performance ratio of 0.96. Excellent performance at low light conditions was also observed. However, its field performance was heavily impacted by soiling, which typically led to a 5 to 10% loss in the current output after several months. Further, the device’s outdoor performance also showed a three-stage degradation process, including (1) an initial slow degradation in the first two years (about -1%/year), (2) a stable period with negligible performance loss from year 2 to year 3.5 and (3) a rapid degradation in the last year (about -5%/year).

With the improvement of surface passivation, bulk recombination is becoming an indispensable and decisive factor to assess the limiting efficiency ( η lim ) of crystalline silicon (c-Si) solar cells. In simultaneous consideration of surface and bulk recombination, a modified model of η lim   evaluation is developed. Surface recombination is directly depicted with contact selectivity while bulk recombination is revised on the aspects of ideality factor and wafer thickness. The η lim of cutting-edge photovoltaic technologies, double-side tunneling-oxide passivating contact (TOPCon) and silicon heterojunction (SHJ) solar cells, are numerically simulated using the new model as 28.73% and 29.00%, respectively. Hybrid solar cells consisting of n-type TOPCon contact and p-type SHJ contact can approach an η lim as high as 29.18% at the optimal wafer thickness ( W opt ) of 103 μm . Our results are instructive in accurately assessing efficiency potential and accordingly optimizing design strategies of c-Si solar cells.

STC power control of PV modules supply requires testing large samples of modules with low uncertainty. This paper analyses the feasibility of outdoor measurements with the modules kept at their operating positions. The classical procedure of recording I-V curves and translating them to STC in accordance with IEC 60891 using the cell temperature directly observed at a few points of the rear of the module entails uncertainties larger than 3% (k=2), which is too much for this procedure being accepted in quality controls with contractual consequences. A convenient procedure for overcoming this barrier consists in comparing the I-V curves of a tested and a reference module of the same type, both working under the same operating conditions. The latter is mostly secured if they are in adjacent positions. However, when the procedure is applied to large samples of PV modules kept in their operating position, the distance between both modules can reach tens of meters and significant inter-module temperature differences can arise. An artifice for counterbalancing these differences consists of estimating the temperature of the tested module and the “true” temperature of the reference module, as deduced from the V OC measurement, by the temperature difference observed at their respective back-sheets in a central position. This allows the measured power values to be corrected and provides clues to estimating the uncertainty of the results. This procedure has been applied in seven testing campaigns, carried out at commercial PV plants. Dedicated instrumentation, based on two radio linked I-V tracers, allowing the simultaneous measurement of the I-V curves and of the temperature at the centres of the reference and the tested modules, has been developed for that. The resulting uncertainties are slightly larger than those corresponding to high-quality solar simulators, but still low enough for dealing, in practice, with strict quality control requirements.

Single junction crystalline silicon (c-Si) solar cells are reaching their practical efficiency limit while perovskite/c-Si tandem solar cells have achieved efficiencies above the theoretical limit of single junction c-Si solar cells. Next to low-thermal budget silicon heterojunction architecture, high-thermal budget carrier-selective passivating contacts (CSPCs) based on polycrystalline-SiO x (poly-SiO x) also constitute a promising architecture for high efficiency perovskite/c-Si tandem solar cells. In this work, we present the development of c-Si bottom cells based on high-temperature poly-SiO x CSPCs and demonstrate novel high-efficiency four-terminal (4T) and two-terminal (2T) perovskite/c-Si tandem solar cells. First, we tuned the ultra-thin, thermally grown SiO x. Then we optimized the passivation properties of p-type and n-type doped poly-SiO x CSPCs. Here, we have optimized the p-type doped poly-SiO x CSPC on textured interfaces via a two-step annealing process. Finally, we integrated such bottom solar cells in both 4T and 2T tandems, achieving 28.1% and 23.2% conversion efficiency, respectively.