Rachel Havranek

and 3 more

Clumped isotope thermometry (T(∆47)) of soil carbonates provides an estimate of soil temperature at the time of mineral formation. Historically, that temperature has been interpreted to represent a warm-season soil temperature based on modern calibration studies largely done in (very) coarse-grained soils. Additionally, T(∆47) gives us an estimate of the oxygen isotope composition of soil water (δ18Ow) in the past, but previous calibration work has not generated independent δ18Ow datasets with which to understand these archives. Here, we present a modern calibration study of pedogenic carbonate clumped isotope thermometry in three soils in Colorado and Nebraska, USA, that have a fine-medium grain size, contain clay, and are representative of many carbonate-bearing paleosols preserved in the rock record. At two of the three sites, Briggsdale, CO and Seibert, CO, T(∆47) overlaps with mean annual air temperature (MAAT), and the calculated δ18Ow overlaps within uncertainty with measured δ18Ow at carbonate bearing depths. At the third site in Oglala National Grassland, NE, mean T(∆47) is 9 – 10°C warmer than MAAT, and the calculated δ18Ow has a significantly higher isotope value than any observations of δ18Ow. At all three sites, even in the fall season, δ18Ow values at carbonate bearing depths indicate little to no evaporative enrichment of heavy isotopes. Moreover, δ18Ow values overlap with precipitation isotope values from spring precipitation. Altogether, these data indicate that soil grain size affects pedogenic carbonate formation, and highlight a need for continued research in modern systems that emulate key features of the geologic record.