Refractory black carbon (rBC) is a primary aerosol species, produced through incomplete combustion, that absorbs sunlight and contributes to positive radiative forcing. The overall climate effect of rBC depends on its spatial distribution and atmospheric lifetime, both of which are impacted by the efficiency with which rBC is transported or removed by convective systems. These processes are poorly constrained by observations. It is especially interesting to investigate rBC transport efficiency through the Asian Summer Monsoon (ASM) since this meteorological pattern delivers vast quantities of boundary layer air from Asia, where rBC emissions are high, to the upper troposphere/lower stratosphere (UT/LS) where the lifetime of rBC is expected to be long. Here we present in-situ observations of rBC made during the Asian Summer Monsoon Chemistry and Climate Impact Project (ACCLIP) of summer, 2022. We use observed relationships between rBC and CO in ASM outflow to show that rBC is removed nearly completely (>98%) from uplifted air, and that rBC concentrations in ASM outflow are statistically indistinguishable from the UT/LS background. We compare observed rBC and CO concentrations to those expected based on two chemical transport models and find that the models reproduce CO to within a factor of 2 at all altitudes while rBC is overpredicted by a factor of 20-100 at altitudes associated with ASM outflow. We find that the rBC particles in recently convected air have thinner coatings than those found in the UTLS background, suggesting non-zero transport of rBC number that is not relevant to concentration.

The Asian Summer Monsoon (ASM) has garnered attention in recent years for its impacts on the composition of the upper troposphere and lower stratosphere (UTLS) via deep convection. A recent observational effort into this mechanism, the Asian summer monsoon Chemical and CLimate Impact Project (ACCLIP), sampled the composition of the ASM UTLS over the northwestern Pacific during boreal summer 2022 using two airborne platforms. In this work, we integrate Lagrangian trajectory modeling with convective cloud top observations to diagnose ASM convective transport which contributed to ACCLIP airborne observations. This diagnostic is applied to explore the properties of convective transport associated with prominent ASM sub-systems, revealing that convective transport along the East Asia Subtropical Front generally contained more pollutants than from South Asia, for species ranging in lifetime from days to months. The convective transport diagnostic is used to isolate three convective transport events over eastern Asia which had distinct chemical tracer relationship slopes, indicating the different economical behaviors of the contributing source regions. One of these transport events is explored in greater detail, where a polluted air mass was sampled from convection over the Northeast China Plain. This event was largely confined to 12-15 km altitude, which may be high enough to impact the composition of the stratosphere. Overall, the presented diagnosis of convective transport contribution to ACCLIP airborne sampling indicates a key scientific success of the campaign and enables process studies of the climate interactions from the two ASM sub-system.