New estimates of stratospheric age of air from halocarbon measurements
of air samples collected by a balloon-borne cryogenic air sampler over
Japan
Abstract
The stratospheric circulation is considered to be strengthened in
response to the increase of atmospheric greenhouse gases, but supporting
observational evidence has not been provided. To diagnose stratospheric
transport, the mean age of air, the transit time of an air parcel from
the troposphere to the stratosphere, has been estimated from
measurements of trace gases, typically CO2 and SF6. Here we present and
evaluate the age of air derived from halocarbon measurements of air
samples collected at 15–35 km altitudes over Japan in 2020. The ages of
air estimated from HFC-23, HFC-227ea and PFC-218 were almost constant at
~5 yr above ~25 km altitude, in general
agreement to those derived from CO2 and SF6. We also examine the age of
air estimated from multiple tracers for future use of upcoming data
towards improving assessment of the long-term trend of the stratospheric
circulation.