Abstract
Zinc (Zn) is biogeochemically significant due to its crucial role in
biological processes. In the global ocean, there is an apparent coupling
between the concentrations of zinc and silicon (Si), and there is a
consistent ratio between the two. However, this coupling is observed to
be disrupted in the North Pacific Ocean. It has been suggested that this
disruption is due to Zn that originates on the continental shelf.
However, this explanation relied on the particular circulation field
used in the model described in the relevant study. The aim of the
current study was to use more realistic circulation fields as the basis
of a more accurate evaluation of deep circulation and export production
in the North Pacific. We also aimed to analyze the impact of uptake
parameters, continental-shelf supply, and regeneration of Zn on the
observed Zn–Si decoupling in the North Pacific. Sensitivity experiments
employing two distinct circulation fields were performed. It was found
that the two circulation fields yielded different decoupling influences:
continental-shelf supply or regeneration. A comparison between the two
circulation fields also revealed discrepancies in the concentration of
regenerated Zn. The main factors causing these differences were found to
be the age of the water masses in the North Pacific and the magnitude of
export production. Greater export production and a more stagnant
circulation field in the North Pacific led to more regenerated Zn and a
higher probability of decoupling without the need for an input of Zn
from the continental shelf.