Observed APO Seasonal Cycles in the Pacific: Estimation of Autumn O2
Oceanic Emissions
Abstract
In this work, we investigated the seasonal cycle of atmospheric
potential oxygen (APO), a unique tracer of air-sea gas exchanges of
molecular oxygen (O2) and carbon dioxide (CO2), expressed as APO = O2 +
1.1×CO2. APO data were obtained from flask air samples collected since
late 1990s at three Japanese ground stations and on commercial cargo
ships sailing between Japan and Australia/New Zealand, North America,
and Southeast Asia. We also analyzed the APO spatial distribution and
seasonal cycles with simulations from an atmospheric transport model,
using climatological oceanic O2 fluxes from a previous study as input.
Model simulations reproduced the observed APO seasonal cycles generally
well, but with larger amplitudes and earlier occurrence of seasonal
minima and maxima than in the observations. Moreover, the observed
seasonal cycles exhibited larger APO enhancements than the simulations
in autumn and early winter, especially in the northern North Pacific at
20°N-60°N. These enhancements remained when refining the comparison by
adjusting the simulated APO peak-to-peak amplitudes and seasonal phases
to the observations. This suggests additional O2 emissions in the North
Pacific, not well expressed in the air-sea O2 fluxes used as input for
our model simulations. The average autumn enhancement at 40°N-60°N was
approximately twice that measured at 20°N-40°N. Confirming previous
studies, our results indicate two distinct mechanisms possibly
contributing to the additional oceanic O2 emissions: outgassing from a
subsurface shallow oxygen maximum at 20°N-40°N and autumn phytoplankton
bloom at 40°N-60°N.