Abstract
Weathering is a natural geological process whereby atmospheric CO2 dissolved in rainwater attacks rocks, partly dissolving them. The CO2 is converted into alkalinity or carbonate minerals that securely store carbon on timescales of >10,000 years. Modelling studies show that if weathering rates can be increased (by selecting the most reactive rocks, increasing reactive surface area), up to an additional 2 Gt CO2 yr-1 could be removed from the atmosphere, ~40% of the amount required by 2100 to meet the Paris Agreement target.
The mining industry extracts gigatonnes of rock each year, generating large amounts of freshly exposed, reactive surface area that could be used as a feedstock for enhanced weathering. Ore deposits with the highest CO2 removal capacity are those mined in high quantities that have an abundance of calcium- and magnesium-bearing silicate minerals [1]. Here, we report the results of an investigation into the reactivity of serpentinised peridotite samples from the Sakatti Cu-Ni-PGE deposit (Finland). The deposit consists of both disseminated and massive sulphides hosted within a large olivine-cumulate body [2]. The material consists primarily of serpentine [Mg3Si2O5(OH)4] and olivine [Mg2SiO4] minerals that have a high potential for CO2 removal via enhanced weathering.
We have conducted a series of laboratory experiments whereby crushed peridotite samples were reacted with CO2-enriched solutions at 25 °C and 50 °C, and 1 bar CO2 (100% CO2). Surface area normalised dissolution rates were determined for various grain sizes, temperatures, mineral compositions (degree of serpentinization) and solution chemistry (with/without a chelating agent).