Cite this paper:Chin. J. Chem. 2023 , 41 , XXX—XXX. DOI:
10.1002/cjoc.202300XXX
Synthesis of L-Hexopyranosyl Fluorides Enabled by Radical
Decarboxylative Fluorination: Assembly of a Pentasaccharide Repeating
Unit Corresponding to
Extracellular Polysaccharide S-88
Zhi Qiao‡,a , Dongwei
Li‡,a , Jingru Gaoa ,
Zijiao Houa , Ningjie
Yana , Ni Songa , Peng
Wang*,a , and Ming
Li*,a,b
a Molecular Synthesis Center, Key Laboratory of Marine
Medicine, Chinese Ministry of Education, Shandong Provincial Key
Laboratory of Glycoscience and Glycotechnology, School of Medicine and
Pharmacy, Ocean University of China, Qingdao 266003,
Chinab Laboratory for Marine Drugs and Bioproducts, Pilot National
Laboratory for Marine Science and Technology, Qingdao 266237,
China