We present the first water vapor profiles encompassing the upper mesosphere of Mars, 100–120 km, far exceeding the maximum altitudes where remote sensing has been able to observe water to date. Our results are based on solar occultation measurements by Atmospheric Chemistry Suite (ACS) onboard the ExoMars Trace Gas Orbiter (TGO). The observed wavelength range around 2.7 μm possesses strong CO2 and H2O absorption lines allowing sensitive temperature and density retrievals. We report a maximum H2O mixing ratio varying from 10 to 50 ppmv at 100–120 km during the global dust storm (GDS) of Martian Year (MY) 34 and around southern summer solstice of MY 34 and 35. During other seasons water remains persistently below ~2 ppmv. We claim that contributions of the MY34 GDS and perihelion periods into the projected hydrogen escape from Mars are nearly equivalent.

The paper presents observations of gravity wave-induced temperature disturbances in the Martian atmosphere obtained with the mid-infrared (MIR) spectrometer, a channel of the Atmospheric Chemistry Suite instrument on board the Trace Gas Orbiter (ACS/TGO). Solar occultation measurements of a CO2 absorption band at 2.7 μm were used for retrieving density and temperature profiles between heights of 20 and 160 km with vertical resolution sufficient for deriving small-scale structures associated with gravity waves. Several techniques for distinguishing disturbances from the background temperature have been explored and compared. Instantaneous temperature profiles, amplitudes of wave packets and potential energy have been determined. Horizontal momentum fluxes and associated wave drag have been estimated. The analyzed data set of 144 profiles encompasses the measurements made over the second half of Martian Year 34, from the Solar longitude 165◦ through 355◦. We observe enhanced gravity wave dissipation/breaking in the mesopause region of 100-130 km. Our analysis shows no direct correlation between the wave amplitude and Brunt-Vaisala frequency. It may indicate that convective instability may not be the main mechanism limiting gravity wave growth in the middle atmosphere of Mars.