Abstract
We develop an existing 1-D photochemistry model to include a
comprehensive description of organic chemistry on Mars that includes the
oxidation products of methane (CH$_4$) and ethane (C$_2$H$_6$),
a longer-chain hydrocarbon that can be used to differentiate between
abiotic and biotic surface releases of CH$_4$. We find that CH$_4$
is most volatile between 20–50 km during Mars’ northern summer, where
the local atmospheric CH$_4$ lifetime lowers to 25–60 years. We
study atmospheric formaldehyde (HCHO) and formic acid (HCOOH), as the
two common oxidation products of CH$_4$ and C$_2$H$_6$, and
acetaldehyde (CH$_3$CHO) and acetic acid (CH$_3$COOH) as unique
products of C$_2$H$_6$. We focus our analysis of these gases at
Mars’ aphelion and perihelion at latitudes between
-30$^{\circ}$ and
30$^{\circ}$, altitudes from the surface to 70 km,
and from a homogeonous initial condition of 50 pptv of CH$_4$ and
C$_2$H$_6$. From this initial condition, CH$_4$ produces HCHO
in a latitude-independent layered structure centred at 20–30 km at
aphelion with column-averaged mixing ratios of 10$^{-4}$ pptv,
and oxidation of C$_2$H$_6$ produces HCHO at 10$^{-2}$
pptv. Formic acid has an atmospheric lifetime spanning 1–10 sols below
10 km that shows little temporal or zonal variability, and is produced
in comparable abundances (10$^{-5}$ pptv) by the oxidation of
C$_2$H$_6$ and CH$_4$. We also find that oxidation of 50 pptv
of C$_2$H$_6$ results in 10$^{-3}$ pptv of CH$_3$CHO and
10$^{-4}$ pptv of CH$_3$COOH. Subsequent UV photolysis of this
CH$_3$CHO results in 10$^{-4}$ pptv of atmospheric CH$_4$,
potentially representing a new atmospheric source of Martian CH$_4$.