EFFECTS OF LONG-TERM CLIMATE CHANGES AND GEOCHEMICAL PROCESSES ON
MERCURY ACCUMULATION ON SOUTH AMERICAN AND AFRICAN MARGINS DURING THE
LAST GLACIAL/INTERGLACIAL CYCLE
Abstract
Marine sediments from the Western and Eastern South Atlantic continental
margins are used to reconstruct mercury (Hg) accumulation over the last
glacial/interglacial cycle. Sediment core GL-1248, collected from the
continental slope off northeastern Brazil, and sediment core ODP1077,
retrieved from the Congo deep-sea fan area, both dated to the last 128
ka and 130 ka respectively. Mercury concentrations in GL-1248 ranged
between 14.95 and 69.43ng/g, and varied with periodicities of 56 ka and
900 yr suggesting the presence of glacial-interglacial changes and
millennial-scale variability respectively. Parallel trends of Hg and
XRF-Fe plots suggest that following atmospheric Hg deposition onto the
continent, Hg is incorporated with iron (Fe) minerals before
transportation and eventual immobilization at the NE Brazil continental
slope. Mercury concentrations in ODP1077 varied significantly, having
concentrations between 23.12 ng/g and 256 ng/g, and its plot exhibits an
anti-phase pattern with the Fe/Ca ratio plot, that distinguishes between
periods of increased and decreased terrigenous material delivery. This
inverse trend in the plots of mercury concentration and Fe/Ca ratio
shows that during periods of increased (decreased) terrigenous material
delivery, less (more) mercury accumulates in the marine sediment.
Although Hg concentration is poorly correlated with total organic carbon
(TOC), it correlates positively with XRF-Ca implying that marine organic
matter played a significant role in mercury distribution and
accumulation in the ODP1077 marine sediment core. Despite the fact that
both marine sediment cores were retrieved from the tropics and cover the
same glacial/interglacial periods, their mercury variations and the main
drivers of mercury accumulations are dissimilar. Accordingly, we
identified two different pathways by which mercury is incorporated into
marine sediments for prolonged storage and inclusion in the global
mercury biogeochemical cycle. The outcome of this study suggests that
regional climate processes and geochemical conditions are essential to
Hg variations in environmental archives. Another obvious finding is that
the source of sedimentary organic carbon is a key determinant of their
affinity for mercury.