Thermal Pressure in the Laser Heated Diamond Anvil Cell: A Quantitative
Study and Implications for the Density vs. Mineralogy Correlation of the
Mantle
Abstract
We present the first quantitative measurements of the magnitude and
gradient of thermal pressure in a laser heated diamond anvil cell
(LHDAC). The observed thermal pressure is strongly localized and follows
the distribution of the laser hotspot. The magnitude of the thermal
pressure is of the order of the thermodynamic thermal pressure (ad) with
gradients between 0.5 – 1.0 GPa/10 um. This poses constraints on
pressure determinations during PVT equation of state measurements when
using a LHDAC. We show that an incomplete account of thermal pressure in
PVT experiments can lead to distortions of the coveted depth versus
mineralogy correlation. However, the ability to spatially resolve
thermal pressure in a LHDAC opens avenues to measure thermodynamic
derivative properties, which are important for comprehensive
thermodynamic descriptions of the interior of planets.