Geochemistry of paleokarst-hosted uranium anomalies at Abu Zarab area,
southwestern Sinai, Egypt
Abstract
Abu Zarab locality is a part from Um Bogma area in southwestern Sinai,
Egypt, where paleokarsts are widespread, especially in carbonate rocks.
Abu Zarab area is covered by Carboniferous carbonate rocks containing
several paleokarsts. One of these paleokarsts was selected to
geochemical investigation. The paleokarst was dissected by three
excavated trenches constructed by Nuclear Materials Authority team to
reveal its geologic features. The paleokarst is filled with lateritic
components represented mainly, by gibbsite, ferruginous siltstone and
clay minerals.
Twelve samples were collected from the walls of these trenches and
chemically analyzed for this purpose in term of major oxides, traces and
rare earth elements. The geochemical data of the major oxides display
three important geochemical processes in the lateritic components of the
paleokarst: (1) Enrichment of aluminum, iron and manganese; (2)
depletion of calcium and magnesium (3) silicon experienced both
depletion and enrichment. The geochemical data of trace and rare earth
elements (REE) display enrichment of U, Cu, Pb, Zn, Ag, As and Cd with
obvious enrichment of REE and conversely some elements were depleted
such as V, Cr and Ga. It also, noticed that uranium has strong positive
correlation with both iron and Aluminum.
This paper attempts to establish the relation between uranium and other
elements in the paleokarst conditions. It is more likely, according to
geochemical features of radioactive elements, that the uranium
enrichment process was postdating laterite formation and the iron played
an important role in capturing and trapping uranium.