Abstract
Heat transport plays a crucial role in igneous processes, and the
thermal evolution of the interiors of terrestrial bodies. Thermal
conductivity is a product of density (ρ), thermal diffusivity (D) and
heat capacity (CP). We measured Dand CPas a function of temperature for
a suite of planetary analog lavas relevant to the Moon, Mars, Mercury,
Io and Vesta. Heat capacity measurements were conducted by differential
scanning calorimetry (DSC) on glasses and liquids covering temperatures
from 400 to 1750 K, Dmeasurements were conducted by laser-flash analyses
(LFA) on glasses from room temperature up to their melting point
slightly above the glass transition (Tg), and densities were already
known. Our results demonstrate that the variability of Dand CPis very
composition-specific, making thermal conductivity (k= DρCP) strongly
composition-dependent. We present an empirical model to estimate Dof
glasses as a function of temperature and composition, with 2σ
uncertainty of 0.040 mm2s-1. Thermal diffusivity of the corresponding
melt can be calculated with an uncertainty of 0.044 mm2s-1, but only
independent of temperature. The model for Dpresented here, in
combination with already available models to calculateCPand ρ, allows to
predict thermal conductivity for a wide range of compositions for
glasses and melts relevant to major planetary objects in the solar
system. We show that basaltic liquids have thermal conductivities
between 1.0 and 1.7 Wm-1K-1, about half that of the mantle from which
they are generated, and therefore partial melting of ascending mantle
leads to a positive feedback that promotes high melt fractions. The
chemical dependence of ksuggests that this effect may have been more or
less effective on different planetary bodies and at different times in
their evolution.