Abstract
Dissolved inorganic carbon (DIC) and total alkalinity (TA) were sampled
in December, 2018 and May, 2019 in the Exclusive Economic Zone (EEZ) of
Qatar in the Arabian Gulf. pCO2 calculated in surface
seawater averaged 459 ± 61 matm and was supersaturated with respect to
the atmosphere. The region was degassing CO2 to the
atmosphere and the flux was about 1.25 mmol C m-2
d-1. The origin of this excess CO2
must be due to CaCO3 precipitation. The horizontal
relationship between salinity-normalized total alkalinity (NTA) and
dissolved inorganic carbon (NDIC) showed that CaCO3
formation was more important, relative to net biological productivity,
than in the open ocean. The tracer Alk* has values primarily determined
by CaCO3 formation and values of Alk* ranged from -50 to
-310 mmol kg-1, which is consistent with substantial
CaCO3 formation. DAlk* increased with increasing
distance northward from Hormuz. The rate of calcification calculated
from the air-sea flux of CO2 (5.6 mmol C
kg-1 y-1) and from DAlk* (5.9 mmol C
kg-1 y-1) agreed well. However,
CaCO3 formation by net calcification in coral reefs is
unlikely as they have limited distribution and have been severely
damaged by past coral bleaching. There are high concentrations of excess
particulate Ca in the water column that cannot be accounted for by input
of CaCO3-rich Qatari dust. Carbonate forming plankton
are absent in the water column. We propose that abiological,
heterogeneous calcite precipitation (HCP) may be occurring. The
mechanism is unknown but nucleation by CaCO3-rich Qatari
dust may assist this process.