Coastal wetlands play a significant role in the storage of ‘blue carbon’, indicating their importance in the carbon biogeochemistry in the coastal zone and in global climate change mitigation strategies. We present airborne eddy-covariance observations of CO2 and CH4 fluxes collected in southern Florida as part of the NASA BlueFlux mission during April 2022, October 2022, February 2023, and April 2023. The flux data generated from this mission consists of over 100 flight hours and more than 6000 km of horizontal distance over coastal saline and freshwater wetlands. We find that the spatial and temporal heterogeneity in CO2 and CH4 exchange is primarily influenced by season, vegetation type, ecosystem productivity, and soil inundation. The largest CO2 uptake fluxes of more than -20 µmol m-2 s-1 were observed over mangroves during all deployments and over swamp forests during flights in April. The greatest CH4 effluxes of more than 250 nmol m-2 s-1 were measured at the end of the wet season in October 2022 over freshwater marshes and swamp shrublands. Although the combined Everglades National Park and Big Cypress National Preserve region was a net sink for carbon, CH4 emissions reduced the ecosystem carbon uptake capacity (net CO2 exchange rates) by 11-91%. Average total net carbon exchange rates during the flight periods were -4 to -0.2 g CO2-eq m-2 d-1. Our results highlight the importance of preserving mangrove forests and point to potential avenues of further research for greenhouse gas mitigation strategies.

Heterogeneous chemical cycles of pyrogenic nitrogen and halides influence tropospheric ozone and affect the stratosphere during extreme pyrocumulonimbus (PyroCB) events. We report field-derived N2O5 uptake coefficients, γ(N2O5), and ClNO2 yields, φ(ClNO2), from two aircraft campaigns observing fresh smoke in the lower and mid troposphere and processed/aged smoke in the upper troposphere and lower stratosphere (UTLS). Derived φ(ClNO2) varied across the full 0–1 range but was typically < 0.5 and smallest in a PyroCB (< 0.05). Derived γ(N2O5) was low in agricultural smoke (0.2–3.6 ×10-3), extremely low in mid-tropospheric wildfire smoke (0.1 × 10-3), but larger in PyroCB processed smoke (0.7–5.0 × 10–3). Aged BB aerosol in the UTLS had a higher median γ(N2O5) of 17 × 10–3 that increased with sulfate and liquid water, but that was nevertheless 1–2 orders of magnitude lower than values for aqueous sulfuric aerosol used in stratospheric models.

As the Arctic climate rapidly warms, there is a critical need for understanding variability and change in the Arctic carbon cycle, but a lack of long-term observations has hindered progress. This work analyzes and interprets measurements of atmospheric carbon dioxide (CO2) mixing ratios from long-term on-ice measurements (the O-Buoy Network), as well as coastal observatories from 2009-2016. The on-ice measurements show smaller seasonal amplitudes when compared to the coastal observatories, in contrast to the general observation of poleward increases of seasonal cycle amplitude. Average on-ice mixing ratios were lower than their coastal counterparts during the winter and spring months, contradicting the expectation that wintertime presents a poleward increasing gradient of CO2. We compare the observations to CO2; simulated in an updated version of the GEOS-Chem 3-D chemical transport model, which includes new tracers of airmass history and CO2; sources and sinks. The model reproduces the observed features of the seasonal cycle and shows that terrestrial biosphere fluxes and synoptic transport explain most CO2; variability over the surface of the Arctic Ocean. Interannually, the coastal observations were more comparable in overall CO2; growth than concurrent measurements over sea ice. We find evidence indicating the presence of ocean gas exchange in and around sea ice during periods where this growth discrepancy occurs. Periods with large spatial gradients are examined, showing that release of CO2; from Arctic waters in years with low sea ice concentration could possibly contribute to the greater interannual increase of CO2; over sea ice compared to land.

Dry deposition is one of the driving factors behind ozone-meteorology relationships. We examine the response of ozone deposition to heat and dry anomalies using three long-term co-located ecosystem-scale carbon dioxide, water vapor and ozone flux measurement records. We find that, as expected, canopy stomatal conductance generally decreases during days with dry air or soil. However, during hot days, concurrent increases in non-stomatal conductance are inferred at all three sites, which may be related to several temperature-sensitive processes not represented in the current generation of big-leaf models. This may offset the reduction in stomatal conductance, leading to smaller net reduction, or even net increase, in total deposition velocity. We find the response of deposition velocity to soil dryness may be related to its impact on photosynthetic activity, though considerable variability exists. Our findings emphasize the need for better understanding and representation of non-stomatal ozone deposition processes.