Quantification of the water age and submarine groundwater discharge in a
typical semi-enclosed bay: Using stable oxygen (18O) and radioactive
radium (228Ra) isotopes
Abstract
Nutrient inputs through submarine groundwater discharge (SGD) play a
significant role in sustaining primary productivity and nutrient cycling
in coastal areas. Currently, various geochemical isotopes are used to
trace the SGD processes. However, mass balance models of stable water
isotopes (2H and 18O) are seldom
used in SGD estimating. In this study, mass balance models of
18O and radium isotopes were used to estimate the
water age and SGD in Laizhou Bay, China based on the isotope data
sampled in August 2017. The water age ranged from 23.5 to 50.0 days with
an average of 32.1 ± 16.3 days. The SGD flux ranged from 1.29 ×
108 m3 d-1 to 2.84
× 108 m3 d-1 with
an average of (2.07 ± 1.04) × 108 m3
d-1. The sensitivity analysis revealed that estimated
results of the water age and SGD are very sensitive to the
18O value in evaporation, as well as
18O and 228Ra values in groundwater
end-members. Based on the isotope method, the proportion of the Yellow
River discharging into Laizhou Bay was estimated to be less than 27% of
the total discharge. Furthermore, combining water and salt mass balance
models, the submarine fresh groundwater discharge (SFGD) flux ranged
from 0.54 × 107 m3
d-1 to 1.31 × 107
m3 d-1 with an average of (0.93 ±
0.46) × 107 m3
d-1. This study reveals that stable and radium
isotopes can be effectively combined to estimate the water age and SGD,
which may be applied to coastal areas elsewhere.