The Atmosphere-Space Interactions Monitor measures Terrestrial Gamma-Ray Flashes (TGFs) simultaneously with optical emissions from associated lightning activity. We analyzed optical measurements at 180-230 nm, 337 nm and 777.4 nm related to 69 TGFs observed between June 2018 and October 2019. All TGFs are associated with optical emissions with 90% at the onset of a large optical pulse, suggesting that they are connected with the initiation of current surges. A simple model of photon delay induced by cloud scattering suggests that the sources of the optical pulses are from 0.7 ms before to 4.4 ms after the TGFs, with a median of -10±80 μs, and 1-5 km below the cloud top. The pulses have rise times comparable to lightning without identified TGFs, while the FWHM is twice as long. Pulse amplitudes at 337 nm are ∼3 times larger than at 777.4 nm. The results support the leader-streamer mechanism for TGF generation.