Abstract
To investigate CO2 sink capacity in the western Arctic
Ocean (north of 65°N), we conducted underway, ship-based observations of
partial pressures of CO2 (pCO2) and
total dissolved inorganic carbon (TCO2) in surface
seawater in early winter (November 2018). From these two properties of
the seawater inorganic carbon system, we calculated total alkalinity
(TA). In the early winter, surface seawater pCO2 in most
places was lower than atmospheric pCO2. The weighted
mean of the air-sea fluxes of CO2 were calculated to be
-7.5 ± 1.6 mmol m−2 d−1. The
calculated fluxes implied that the area acted as a moderate sink for
atmospheric CO2 in early winter, and its rate of
CO2 uptake was comparable to that (-8.0 ± 1.7 mmol
m−2 d−1) in summer (late
August-September 2017). Spatial variations of surface seawater
pCO2 in the early winter could be attributed mostly to
conservative changes of TCO2 and TA, which together
accounted for more than 70% of the pCO2 variations. In
the marginal ice zone, however, there was a drawdown of surface seawater
pCO2 by 70-90 matm due to horizontal advection of water
with an anomalously high temperature from the Pacific Ocean and its
subsequent cooling. We found that TA was an important determinant of the
spatial variations of pCO2 in the western Arctic Ocean
because of the conservative nature of the changes of TA and
TCO2 during mixing of water masses. This conservative
behavior was observed in both the early winter and summer.