The aim of this work is to understand the formation of primary evaporites—sulfates, borates, and chlorides—in Gale crater using thermochemical modeling to determine constraints on their formation. We test the hypothesis that primary evaporites required multiple wet-dry cycles to form, akin to how evaporite assemblages form on Earth. Starting with a basalt-equilibrated Mars fluid, Mars-relevant concentrations of B and Li were added, and then equilibrated with Gale lacustrine bedrock. We simulated cycles of evaporation followed by groundwater recharge/dilution to establish an approximate minimum number of wet-dry cycles required to form primary evaporites. We determine that a minimum of 250 wet-dry cycles may be required to start forming primary evaporites that consist of borates and Ca-sulfates. We estimate that ~14,250 annual cycles (~25.6 k Earth years) of wet and dry periods may form primary borates and Ca-sulfates in Gale crater. These primary evaporites could have been remobilized during secondary diagenesis to form the veins that the Curiosity rover observes in Gale crater. No LiCl salts form after 14,250 cycles modeled for the Gale-relevant scenario (approximately 106 cycles would be needed) which implies Li may be leftover in a groundwater brine after the time of the lake. No major deposits of borates are observed to date in Gale crater which also implies that B may be leftover in the subsequent groundwater brine that formed after evaporites were remobilized into Ca-sulfate veins.

During the NASA Perseverance rover’s exploration of the Jezero crater floor, purple-hued coatings were commonly observed on rocks. These features likely record past water-rock-atmosphere interactions on the crater floor, and understanding their origin is important for constraining timing of water activity and habitability at Jezero. Here we characterize the morphologic, chemical, and spectral properties of the crater floor rock coatings using color images, visible/near-infrared reflectance spectra, and chemical data from the Mastcam-Z and SuperCam instruments. We show that coatings are common and compositionally similar across the crater floor, and consistent with a mixture of dust, fine regolith, sulfates, and ferric oxides indurated as a result of one or more episodes of widespread surface alteration. All coatings exhibit a similar smooth homogenous surface with variable thickness, color, and spatial extent on rocks, likely reflecting variable oxidation and erosional expressions related to formation and/or exposure age. Coatings unconformably overlie eroded natural rock surfaces, suggesting relatively late deposition that may represent one of the last aqueous episodes on the Jezero crater floor. While more common at Jezero, these coatings may be consistent with rock coatings previously observed in-situ at other landing sites and may be related to duricrust formation, suggesting a global alteration process on Mars that is not unique to Jezero. The Perseverance rover likely sampled these rock coatings on the crater floor and results from this study could provide important context for future investigations by the Mars Sample Return mission aimed at constraining the geologic and aqueous history of Jezero crater.

During the first 2934 sols of the Curiosity rover’s mission 33,468 passive visible/near-infrared reflectance spectra were taken of the surface by the mast-mounted ChemCam instrument on a range of target types. ChemCam spectra of bedrock targets from the Murray and Carolyn Shoemaker formations on Mt. Sharp were investigated using principal component analysis (PCA) and various spectral parameters including the band depth at 535 nm and the slope between 840 nm and 750 nm. Four endmember spectra were identified. Passive spectra were compared to Laser Induced Breakdown Spectroscopy (LIBS) data to search for correlations between spectral properties and elemental abundances. The correlation coefficient between FeOT reported by LIBS and BD535 from passive spectra was used to search for regions where iron may have been added to the bedrock through oxidation of ferrous-bearing fluids, but no correlations were found. Rocks in the Blunts Point-Sutton Island transition that have unique spectral properties compared to surrounding rocks, that is flat near-infrared (NIR) slopes and weak 535 nm absorptions, are associated with higher Mn and Mg in the LIBS spectra of bedrock. Additionally, calcium-sulfate cements, previously identified by Ca and S enrichments in the LIBS spectra of bedrock, were also shown to be associated with spectral trends seen in Blunts Point. A shift towards steeper near-infrared slope is seen in the Hutton interval, indicative of changing depositional conditions or increased diagenesis.

Through rover missions and martian meteorites received on Earth, the surface of Mars has showed unexpectedly elevated concentrations of transition metals usually measured in minor and trace concentrations in silicate rocks compared to the average crust. Gale crater presents one of the most diverse geological records in terms of its complex fluid and magmatic history described through the sedimentary and igneous records, respectively. Transition metals, such as Mn, Co, Ni, Cu, and Zn, are highly concentrated within various sedimentary rocks and diagenetic features, suggesting their mobilization through fluid circulation. This paper presents the first compilation of elevated concentrations of transition metals measured by the Curiosity rover and reviews the origin of such metals in Gale crater, highlighting the existence of a hydrothermal or magmatic-hydrothermal deposit in its vicinity. The discovery of felsic magmatism on Mars opens up to novel perspectives in terms of the type of metal deposits that current and future exploration could evidence at the surface of Mars and raise questions about the global abundance of such metals. Constraining the abundance of transition metals is also a central question for exobiology purposes. Because on Earth living organisms use transition metals for their survival and functioning, should live have arisen on Mars, the availability of such chemical elements at the surface could have been essential for its development. An accurate assessment of in situ metal resources and potential risks for health will be key for the preparation of human exploration of Mars as recently announced by NASA.