Wind and fetch dependence of gas transfer velocity in an Arctic sea-ice
lead determined from eddy covariance CO flux measurements
Abstract
The air-water exchange of trace gases such as CO is usually
parameterized in terms of a gas transfer velocity, which can be derived
from direct measurements of the air-sea gas flux. The transfer velocity
of poorly soluble gases is driven by near-surface ocean turbulence,
which may be enhanced or suppressed by the presence of sea ice. A lack
of measurements means that air-sea fluxes in polar regions, where the
oceanic sink of CO is not well known, are generally estimated using
open-ocean transfer velocities scaled by ice fraction. Here, we describe
direct determinations of the CO gas transfer velocity from eddy
covariance flux measurements at a sea-ice lead during the summer-autumn
transition in the central Arctic Ocean. CO uptake by the lead water is
determined using flux footprint analysis of water-atmosphere and
ice-atmosphere flux measurements made under conditions (low humidity and
high CO signal) that minimise errors due to humidity cross-talk. The
mean gas transfer velocity over the lead is found to have a quadratic
dependence on wind speed:
= 0.189
which is 25 to 30% lower than commonly used open-ocean
parameterizations. As such, current estimates of polar ocean carbon
uptake are likely to overestimate gas exchange rates in typical
summertime conditions of weak convective turbulence. The gas transfer
velocities also exhibit a dependence on the dimension of the lead, via
its impact on fetch length and hence sea state. Scaling transfer
velocity parameterizations for regional gas exchange estimates will
therefore require incorporating lead width data.