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A new halocarbon absorption model based on HITRAN cross-section data and new estimates of halocarbon instantaneous clear-sky radiative forcing
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  • Stefan Alexander Buehler,
  • Manfred Brath,
  • Oliver Lemke,
  • Øivind Hodnebrog,
  • Robert Pincus,
  • Patrick Eriksson,
  • Iouli Gordon,
  • Richard Larsson
Stefan Alexander Buehler
Universität Hamburg

Corresponding Author:[email protected]

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Manfred Brath
Universität Hamburg
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Oliver Lemke
Universität Hamburg
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Øivind Hodnebrog
CICERO Center for International Climate Research
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Robert Pincus
Columbia University
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Patrick Eriksson
Chalmers University of Technology
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Iouli Gordon
Harvard-Smithsonian Center for Astrophysics
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Richard Larsson
Universität Hamburg
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Abstract

The article describes a new practical model for the infrared absorption of chlorofluorocarbons and other gases with dense spectra, based on HITRAN absorption cross-sections. The model is very simple, consisting of frequency-dependent polynomial coefficients describing the pressure and temperature dependence of absorption. Currently it is implemented for the halocarbon species required by the Radiative Forcing Model Intercomparison Project (RFMIP). This approach offers practical advantages compared to previously available options, and is traceable, since the polynomial coefficients follow directly from the laboratory spectra. The model is applied to the problem of computing instantaneous clear-sky halocarbon radiative efficiencies and present day radiative forcing. Results are in reasonable agreement with earlier assessments that were carried out with the less explicit Pinnock method, and thus broadly validate that method. Overall, halocarbons are responsible for a substantial share of the present-day forcing, 0.573 Watt/squaremeter (instantaneous clear-sky at the TOA), corresponding to approximately 20% of the total anthropogenic forcing, or 44% compared to anthropogenic CO2 forcing alone.