Recent observations from the ExoMars Trace Gas Orbiter (TGO) have revealed the presence of hydrogen chloride (HCl) in the martian atmosphere. HCl shows strong seasonality, primarily appearing during Mars’ perihelion period and rapidly decreasing afterwards faster than projected from photolysis and gas-phase chemistry. HCl also shows anti-correlation with atmospheric water ice. One candidate explanation is heterogeneous chemistry. We present the first results from a heterogeneous chlorine chemistry scheme incorporated into a Mars global climate model (GCM), with atmospheric dust/water ice parameterized as an HCl source/sink respectively. Results were compared against a Mars GCM with gas-phase only chlorine chemistry and observations from TGO’s Atmospheric Chemistry Suite (ACS). We found that the heterogeneous scheme significantly improved the modelled HCl seasonal, latitudinal, and vertical distribution, supporting a crucial role for heterogeneous chemistry in Mars’ chlorine cycle. Remaining discrepancies show that further work is needed to characterise the exact aerosol reactions involved.

Detecting trace gases such as hydrogen chloride (HCl) in Mars' atmosphere is among the primary objectives of the ExoMars Trace Gas Orbiter (TGO) mission. Terrestrially, HCl is closely associated with active volcanic activity, so its detection on Mars was expected to point to some form of active magmatism/outgassing. However, after its discovery using the mid-infrared channel of the TGO Atmospheric Chemistry Suite (ACS MIR), a clear seasonality was observed, beginning with a sudden increase in HCl

We present the first water vapor profiles encompassing the upper mesosphere of Mars, 100–120 km, far exceeding the maximum altitudes where remote sensing has been able to observe water to date. Our results are based on solar occultation measurements by Atmospheric Chemistry Suite (ACS) onboard the ExoMars Trace Gas Orbiter (TGO). The observed wavelength range around 2.7 μm possesses strong CO2 and H2O absorption lines allowing sensitive temperature and density retrievals. We report a maximum H2O mixing ratio varying from 10 to 50 ppmv at 100–120 km during the global dust storm (GDS) of Martian Year (MY) 34 and around southern summer solstice of MY 34 and 35. During other seasons water remains persistently below ~2 ppmv. We claim that contributions of the MY34 GDS and perihelion periods into the projected hydrogen escape from Mars are nearly equivalent.

Temperature and density in the upper Martian atmosphere, above ~100 km, are key diagnostic parameters to study processes of the species’ escape, investigate the impact of solar activity, model the atmospheric circulation, and plan spacecraft descent or aerobraking maneuvers. In this paper, we report vertical profiling of carbon dioxide (CO2) density and temperature from the Atmospheric Chemistry Suite (ACS) solar occultations onboard the ExoMars Trace Gas Orbiter (TGO). A strong CO2 absorption band near 2.7 μm observed by the middle infrared spectrometric channel (ACS MIR) allows the retrieval of the atmospheric thermal structure in a large altitude range, from 20 to 180 km. We present the latitudinal and seasonal climatology of the thermal structure for 1.5 Martian years (MYs), from the middle of MY 34 to the end of MY 35. The results show the variability of distinct atmospheric layers, such as a mesopause (derived from 70 to 150 km) and homopause, changing from 80-90 km at aphelion to 100-110 km at perihelion. Some short-term homopause fluctuations are also observed depending on the dust activity.

On Mars, saturation is the major factor constraining the vertical distribution of water vapor. Recent measurements of water and temperature profiles showed that water can be strongly supersaturated at and above the level where clouds form during aphelion and perihelion seasons. Since 2018, the near-infrared spectrometer (NIR) of the Atmospheric Chemistry Suite onboard the Trace Gas Orbiter has measured H2O and temperature profiles using solar occultation in the infrared from below 10 km to 100 km of altitude. Here we provide the first long-term monitoring of the water saturation state. The survey spans 2 Martian years from Ls=163° of MY34 to the Ls=180° of MY36. We found that water is often supersaturated above aerosol layers. In the aphelion season, water mixing ratio above 40 km in the mid-to-high latitudes was below 3 ppmv and yet is found to be supersaturated. Around perihelion, water is also supersaturated above 60 km with a mixing ratio of 30-50 ppmv. Stronger saturation is observed during the dusty season in MY35 compared to what was observed in MY34 during the Global Dust Storm and around perihelion. Saturation varied between evening and morning terminators in response to temperature modulation imparted by thermal tides. Although water vapor is more abundant in the evening, colder morning temperatures induce a daily peak of saturation. This dataset establishes a new paradigm for water vapor on Mars, revealing that supersaturation is nearly ubiquitous, particularly during the dust season, thereby promoting water escape on an annual average.

The mid-infrared channel of the Atmospheric Chemistry Suite (ACS MIR) onboard the ExoMars Trace Gas Orbiter is capable of observing the infrared absorption of ozone (O3) in the atmosphere of Mars. During solar occulations, the 003-000 band (3000-3060 cm-1) is observed with spectral sampling of ˜0.045 cm-1. Around the equinoxes in both hemispheres and over the southern winters, we regularly observe around 200-500 ppbv of O3 below 30 km. The warm southern summers, near perihelion, produce enough atmospheric moisture that O3 is not detectable at all, and observations are rare even at high northern latitudes. During the northern summers, water vapour is restricted to below 10 km, and an O3 layer (100-300 ppbv) is visible between 20-30 km. At this same time, the aphelion cloud belt forms, condensing water vapour and allowing O3 to build up between 30-40 km. A comparison to vertical profiles of water vapour and temperature in each season reveals that water vapour abundance is controlled by atmospheric temperature, and H2O and O3 are anti-correlated as expected. When the atmosphere cools, over time or over altitude, water vapour condenses (observed as a reduction in its mixing ratio) and the production of odd hydrogen species is reduced, which allows O3 to build up. Conversely, warmer temperatures lead to water vapour enhancements and ozone loss. The LMD Mars Global Climate Model is able to reproduce vertical structure and seasonal changes of temperature, H2O, and O3 that we observe. However, the observed O3 abundance is larger by a factor of 2-6, indicating important differences in the rate of odd-hydrogen photochemistry.

Carbon monoxide is a non-condensable species of the Martian atmosphere produced by the photolysis of CO2. Its mixing ratio responds to the condensation and sublimation of CO2; from the polar caps, resulting in seasonal variations of the CO abundance. Since 2018, all three spectrometers of the Atmospheric Chemistry Suite (ACS) onboard the Trace Gas Orbiter have measured CO in infrared bands by solar occultation. Here we provide the first long-term monitoring of the CO vertical distribution at the altitude range from 0 to 80 km for 1.5 Martian years from Ls=163; of MY34 to the end of MY35. We obtained a mean CO volume mixing ratio of ~960 ppm at latitudes from 45S to 45N, mostly consistent with previous observations. We found a strong enrichment of CO near the surface at Ls=100-200; in high southern latitudes with a layer of 3000-4000 ppmv, corresponding to local depletion of CO2. At equinoxes we found an increase of mixing ratio above 50 km to 3000–4000 ppmv explained by the downwelling flux of the Hadley circulation on Mars, which drags the CO enriched air. The general circulation chemical model tends to overestimate the intensity of this process, bringing too much CO. The observed minimum of CO in the high and mid-latitudes southern summer atmosphere amounts to 700-750 ppmv, agreeing with nadir measurements. During the global dust storm of MY34, when the H2O abundance peaks, we see less CO than during the calm MY35, suggesting an impact of HOx chemistry on the CO abundance.