Predicting the impact of changing climate and anthropogenic influences on stream discharge dynamics and baseflow conditions requires insight into the main factors that regulate storage and transfer of water from hillslope aquifers to surface streams. Classically, it is assumed that above a certain scale, hydrological laws involved at small-scale can be simplified, allowing the representation of the landscape and its subsurface in models as a homogeneous hillslope with effective slope, length and hydraulic properties. From a comprehensive analysis of hydrological, geological and geomorphological databases available in the Swiss Alps we provide evidence that such simplification might lead to inaccurate estimates of streamflow dynamics at baseflow. We reveal that recession behavior strongly deviates from that predicted by idealized homogeneous theories. A correlation analysis allows us to identify which key features of the landscape might control this deviation, with particular attention to slope, drainage density, depth to bedrock, and lithology as the main drivers. We summarize the current knowledge of physical mechanisms that could lead to complex hydrological behavior in Alpine contexts, and we finally discuss implications in defining modeling strategies for the Critical Zone community.