Regimes of carbonate subduction as a function of lithospheric mantle
hydration state
Abstract
Using three models of upper mantle hydration state, we quantify the
subsolidus process of mass redistribution within and out of slabs. We
use a numerical model where all major elements in the rock are soluble
and mobile. Our transport model achieves high accuracy in predicting the
energetics and fluid/rock mass balance of subduction zone processes. We
find that most carbonate rich sediments (e.g. eastern Pacific) get
depleted in K while they accumulate Al and Si. Patterns of mass and
concentration changes are not always correlated, reflecting the
antagonistic role of metasomatism versus residual enrichment due to
volatile loss. We find that carbon released to subarc depth is 25.7 –
31.4 Mt C/yr, which corresponds to 51.0 to 61.9 % of trench input,
confirming previous estimates. However, this decarbonation efficiency is
highly heterogeneous. The host slabs of eastern pacific recycle most
carbon back to the mantle wedge, while the cold slabs of western pacific
inject carbon. Slabs decarbonation efficiencies show different
sensitivity to hydration state of the mantle wedge. Transport
(water)-limited slabs, which are sensitive to the AUM hydration state,
are the most numerous and tend to be the largest C emitters. There are
also supply-limited slabs, i.e. not sensitive to the AUM hydration
state, e.g. hot (Mexico) and cold (Honshu) slabs. We first show that
slabs subducting limestones are sensitive to infiltration of
non-volatile elements from underlying igneous sections to drive
metasomatic-decarbonation process by promoting garnet growth. These
insights inform specific regional targets for studying the cycle of
rock-forming elements.