Assessing surface ozone-NOx-VOC sensitivity in major Indian cities using
high resolution TROPOMI observations
Abstract
Policies to regulate severe surface ozone pollution in cities in India
are challenging to develop, due to the complex dependence on precursor
emissions of volatile organic compounds (VOCs) and nitrogen oxides
(NOx), non-linear chemistry leading to ozone formation, and very limited
spatial and temporal surface air quality monitoring. Ratios of
space-based observations of formaldehyde (HCHO), an intermediate
oxidation product of VOCs, and nitrogen dioxide (NO2) have been used to
characterize the sensitivity of surface ozone production to precursor
emissions of VOCs and NOx, but interpretation of these depends on the
local oxidation regime. Here we develop an improved approach in which we
discretize the data into background HCHO due to methane and other
long-lived VOCs (regression intercept) and the local relationship
(regression slope) between HCHO associated with reactive VOCs and NO2.
We apply this to TROPOMI HCHO and NO2 tropospheric columns oversampled
to higher spatial resolution than the native pixel resolution of the
instrument over the ten most populous cities in India. We use GEOS-Chem
to characterize the ozone production regimes and then apply this updated
interpretation of the relationship between HCHO and NO2 to the
oversampled TROPOMI columns to identify the most effective strategies
for regulating ozone and whether these should vary seasonally and
spatially.