In this study, we show that non-thermal collisions can play a significant role in shaping Europa's exospheric structure. Collisions between radiolytically produced O2 and the O produced via electron impact dissociation of O2 play a significant role in affecting the exospheric structure and escape rates. Specifically, O+O2 collisions lead to the production of a non-thermal O2 population, and increase the O2 escape while decreasing the O escape. These collisions are dependent on three specific physical parameters: (1) the density of O2 , (2) the electron impact dissociation rate of O2 , and (3) the O+O2 collision cross section. We demonstrate here that O+O2 collisions affect Europa's atmosphere even in the lowest limits considered. Thus, to more accurately determine the influence O+O2 collisions have on Europa's atmosphere in preparation for the forthcoming spacecraft missions, Europa Clipper and the JUpiter ICy moons Explorer (JUICE), these physical parameters need to be better constrained.