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Rethinking the role of transport and photochemistry in regional ozone pollution: Insights from ozone mass and concentration budgets
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  • Kun Qu,
  • Xuesong Wang,
  • Xuhui Cai,
  • Yu Yan,
  • Xipeng Jin,
  • Mihalis Vrekoussis,
  • Jin Shen,
  • Teng Xiao,
  • Limin Zeng,
  • Yuanhang Zhang
Kun Qu
Peking Univeristy; University of Bremen, Peking Univeristy; University of Bremen
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Xuesong Wang
College of Environmental Sciences and Engineering, College of Environmental Sciences and Engineering

Corresponding Author:[email protected]

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Xuhui Cai
Peking University, Peking University
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Yu Yan
Peking university, Peking university
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Xipeng Jin
Peking University, Peking University
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Mihalis Vrekoussis
Institute of Environmental Physics, University of Bremen, Institute of Environmental Physics, University of Bremen
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Jin Shen
Guangdong Environmental Monitoring Center, Guangdong Environmental Monitoring Center
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Teng Xiao
Peking University, Peking University
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Limin Zeng
College of Environmental Sciences and Engineering, Peking University, College of Environmental Sciences and Engineering, Peking University
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Yuanhang Zhang
State Key Lab, State Key Lab
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Abstract

Understanding the role of transport and photochemistry is essential to alleviate regional ozone pollution. However, budget studies often report conflicting conclusions. Using the modeling results of WRF-CMAQ, we calculated the contributions of both processes to the variation of total ozone mass and mean ozone concentration (noted as ozone mass and concentration budget, respectively) within the atmospheric boundary layer (ABL) of the Pearl River Delta, China. Transport, especially the exchange between ABL and free troposphere, controls the ozone mass budget, whereas local photochemistry drives the rapid increase of ozone concentration in the daytime. Though transport has a limited effect on ozone concentration, its high contribution to the ozone mass budget determines that most ozone emanates from the outside regions. Consequently, the role of transport and photochemistry in ozone pollution may differ, depending on which of the two budgets is considered. Attention should be paid to budget type selections in future studies.