Rethinking the role of transport and photochemistry in regional ozone
pollution: Insights from ozone mass and concentration budgets
Abstract
Understanding the role of transport and photochemistry is essential to
alleviate regional ozone pollution. However, budget studies often report
conflicting conclusions. Using the modeling results of WRF-CMAQ, we
calculated the contributions of both processes to the variation of total
ozone mass and mean ozone concentration (noted as ozone mass and
concentration budget, respectively) within the atmospheric boundary
layer (ABL) of the Pearl River Delta, China. Transport, especially the
exchange between ABL and free troposphere, controls the ozone mass
budget, whereas local photochemistry drives the rapid increase of ozone
concentration in the daytime. Though transport has a limited effect on
ozone concentration, its high contribution to the ozone mass budget
determines that most ozone emanates from the outside regions.
Consequently, the role of transport and photochemistry in ozone
pollution may differ, depending on which of the two budgets is
considered. Attention should be paid to budget type selections in future
studies.