loading page

Excess pCO2 in Surface Seawater of the Arabian Gulf
  • +4
  • James W. Murray,
  • Jassem Al-Thani,
  • Oguz Yigiterhan,
  • Ebrahim Mohd Al-Ansari,
  • Vethamony Ponnumony,
  • Caesar Flonasca Sorino,
  • Daniel B Anderson
James W. Murray
University of Washington

Corresponding Author:[email protected]

Author Profile
Jassem Al-Thani
Qatar University
Author Profile
Oguz Yigiterhan
Qatar University
Author Profile
Ebrahim Mohd Al-Ansari
Qatar University
Author Profile
Vethamony Ponnumony
Qatar University
Author Profile
Caesar Flonasca Sorino
Qatar University
Author Profile
Daniel B Anderson
University of Washington
Author Profile

Abstract

Dissolved inorganic carbon (DIC) and total alkalinity (TA) were sampled in December, 2018 and May, 2019 in the Exclusive Economic Zone (EEZ) of Qatar in the Arabian Gulf. pCO2 calculated in surface seawater averaged 459 ± 61 matm and was supersaturated with respect to the atmosphere. The region was degassing CO2 to the atmosphere and the flux was about 1.25 mmol C m-2 d-1. The origin of this excess CO2 must be due to CaCO3 precipitation. The horizontal relationship between salinity-normalized total alkalinity (NTA) and dissolved inorganic carbon (NDIC) showed that CaCO3 formation was more important, relative to net biological productivity, than in the open ocean. The tracer Alk* has values primarily determined by CaCO3 formation and values of Alk* ranged from -50 to -310 mmol kg-1, which is consistent with substantial CaCO3 formation. DAlk* increased with increasing distance northward from Hormuz. The rate of calcification calculated from the air-sea flux of CO2 (5.6 mmol C kg-1 y-1) and from DAlk* (5.9 mmol C kg-1 y-1) agreed well. However, CaCO3 formation by net calcification in coral reefs is unlikely as they have limited distribution and have been severely damaged by past coral bleaching. There are high concentrations of excess particulate Ca in the water column that cannot be accounted for by input of CaCO3-rich Qatari dust. Carbonate forming plankton are absent in the water column. We propose that abiological, heterogeneous calcite precipitation (HCP) may be occurring. The mechanism is unknown but nucleation by CaCO3-rich Qatari dust may assist this process.