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Trace metal fractional solubility in size-segregated aerosols from the tropical eastern Atlantic Ocean
  • Alex R. Baker,
  • Mingpei Li,
  • Rosie Chance
Alex R. Baker
University of East Anglia, University of East Anglia

Corresponding Author:alex.baker@uea.ac.uk

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Mingpei Li
Newcastle University, Newcastle University
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Rosie Chance
University of York, University of York
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Soluble and total trace metals were measured in 4 size fractionated aerosol samples collected over the tropical eastern Atlantic Ocean. In samples that were dominated by Saharan dust, the size distributions of total iron, aluminium, titanium, manganese, cobalt and thorium were very similar to one another and to the size distributions of soluble manganese, cobalt and thorium. Finer particle sizes (< ~3 µm) showed enhanced soluble concentrations of iron, aluminium and titanium, possibly as a result of interactions with acidic sulfate aerosol during atmospheric transport. The difference in fine particle solubility between these two groups of elements might be related to the hyperbolic increase in the fractional solubility of iron, and a number of other elements, during the atmospheric transport of Saharan dust, which is not observed for manganese and its associated elements. In comparison to elements whose solubility varies during atmospheric transport, the stability of thorium fractional solubility should reduce uncertainties in the use of dissolved concentrations of this element in seawater as a proxy for dust deposition, although this topic requires further work.
Jun 2020Published in Global Biogeochemical Cycles volume 34 issue 6. 10.1029/2019GB006510